An unexpected Rearrangement of Dimethyl-Allyl-2-Hydroxyethyl Quaternary Ammonium Salts in an Alkaline Medium
G H Torosyan
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G H Torosyan: National polytechnic university of Armenia, Armenia
Organic & Medicinal Chemistry International Journal, 2018, vol. 5, issue 2, 53-54
Abstract:
It’s known intramolecular O-benzylation of dimethylbenzyl-2-hydroxyethylammonium chloride at 175-180оС with the formation of dimethylaminoethanol benzyl ether chlorohydrate with a low yield - 5-20% [1]. The same salt undergoes to Sommelet rearrangement in a strong alkaline medium with the formation of corresponding tertiary amine [2].
Keywords: juniper publishers:Medicinal Chemistry; Biochemistry Journal; Pharmacology Journal; biochemical pharmacology; molecular pharmacology; biochemistry; open access journals; peer reviewed journals; Open Access; Journal of Molecular Biochemistry; International Research Journal of Pure and Applied Chemistry; World Journal of Biological Chemistry; Biochemistry and Analytical Biochemistry; Biochemistry & Physiology: Open Access; Molecular Biology International; Plant Biochemistry & Physiology; International Journal of Molecular Sciences; Journal of Clinical and Medical Genomics; Environmental Analytical Chemistry; Medicinal Chemistry; Juniper publishers reivews (search for similar items in EconPapers)
Date: 2018
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Persistent link: https://EconPapers.repec.org/RePEc:adp:jomcij:v:5:y:2018:i:2:p:53-54
DOI: 10.19080/OMCIJ.2018.05.555658
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