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Allium discoloration: the nature of onion pinking and garlic greening

R. Kubec, M. Hrbáčová, R. A Musah and J. Velíšek
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R. Kubec: Department of Food Chemistry and Analysis, Institute of Chemical Technology, Prague, Czech
M. Hrbáčová: Department of Food Chemistry and Analysis, Institute of Chemical Technology, Prague, Czech
R. A Musah: Department of Food Chemistry and Analysis, Institute of Chemical Technology, Prague, Czech
J. Velíšek: Department of Food Chemistry and Analysis, Institute of Chemical Technology, Prague, Czech

Czech Journal of Food Sciences, 2004, vol. 22, issue SpecialIssue, S109-S112

Abstract: Precursors involved in the formation of pink and green-blue pigments during onion and garlic processing, respectively, have been studied. It has been confirmed that the formation of both pigments is of a very similar nature, with (E)-S-(1-propenyl)cysteine sulfoxide (isoalliin) serving as the primary precursor. Upon disruption of the tissue, isoalliin and other S-alk(en)ylcysteine sulfoxides are enzymatically cleaved, yielding prop-1-enylcontaining thiosulfinates [CH3CH = CHS(O)SR; R = methyl, allyl, propyl, 1-propenyl], among others. The latter compounds subsequently react with amino acids to produce the pigments. Whereas the onion and leek-related propyl, prop-1-enyl and methyl derivatives can form pink, pink-red and magenta compounds, those containing the allyl group yield dark blue products after reacting with glycine at pH 5.0.

Keywords: Allium; garlic; onion; discoloration; pigment (search for similar items in EconPapers)
Date: 2004
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Persistent link: https://EconPapers.repec.org/RePEc:caa:jnlcjf:v:22:y:2004:i:specialissue:id:10629-cjfs

DOI: 10.17221/10629-CJFS

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