The Potential to Produce Bio-Based Ammonia Adsorbents from Lignin-Rich Residues

Daniel Chernick, Valerie Dupont () and Andrew B. Ross
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Daniel Chernick: School of Chemical and Process Engineering, University of Leeds, Woodhouse Lane, Leeds LS2 9JT, UK
Valerie Dupont: School of Chemical and Process Engineering, University of Leeds, Woodhouse Lane, Leeds LS2 9JT, UK
Andrew B. Ross: School of Chemical and Process Engineering, University of Leeds, Woodhouse Lane, Leeds LS2 9JT, UK

Clean Technol., 2025, vol. 7, issue 2, 1-24

Abstract: The ammonia adsorption capacity of lignin-rich biomass solids was tested for the first time at low partial pressures (<1.5 kPa) and 20 °C. The biomass samples included untreated tree barks, husks, and peats, as well as the biochars produced by their slow pyrolysis. Proximate and ultimate analyses, lignin content, and metal content are also presented. The untreated biosolids had higher VM/FC ratios, molar H/C, and O/C than the treated biosolids (biochars and treated biochars). A novel methodology is described for the safe generation of gaseous ammonia at predictable low partial pressures from tabletop-scale batch reaction experiments of NaOH with (NH 4 ) 2 SO 4 in aqueous solution, leading to the determination of ammonia adsorption capacities from low-cost experiments. Statistically significantly larger NH 3 adsorption capacities were obtained for the untreated biosolids than for their biochars ( p < 0.001). In contrast, the biochars were found to be poor NH 3 adsorbers without further treatment. The NH 3 adsorption capacities from this study’s biosolids were compared with those of common adsorbent types in the same conditions using the existing literature through equilibrium model interpolation (Dubinin–Astakhov, Toth, and Freundlich) or cubic spline fit from graphical isotherms. Controls consisting of commercially sourced activated carbons (AC) had low adsorption capacities, close to those derived from the literature in the same conditions for similar materials, confirming the methodology’s robustness. The untreated biosolids’ NH 3 adsorption capacities were in the same range as those reported for silica, gamma-alumina, and some of the treated or doped ACs. They also performed better than the undoped, untreated ACs. The work suggests lignin-rich untreated biosolids such as barks and peats are competent low-cost ammonia adsorbents.

Keywords: ammonia; adsorption; tree bark; peat; biochar; Dubinin–Astakhov; Toth; Freundlich (search for similar items in EconPapers)
JEL-codes: Q2 Q3 Q4 Q5 (search for similar items in EconPapers)
Date: 2025
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