Conversion of Levulinic Acid from Various Herbaceous Biomass Species Using Hydrochloric Acid and Effects of Particle Size and Delignification

Indra Neel Pulidindi and Tae Hyun Kim
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Indra Neel Pulidindi: Department of Materials Science and Chemical Engineering, Hanyang University, Ansan 15588, Korea
Tae Hyun Kim: Department of Materials Science and Chemical Engineering, Hanyang University, Ansan 15588, Korea

Energies, 2018, vol. 11, issue 3, 1-12

Abstract: Acid catalyzed hydrothermal conversion of levulinic acid (LA) from various herbaceous materials including rice straw (RS), corn stover (CS), sweet sorghum bagasse (SSB), and Miscanthus (MS) was evaluated. With 1 M HCl, 150 °C, 5 h, 20 g/L solid loading, the yields of LA from untreated RS, CS, SSB and MS based on the glucan content were 60.2, 75.1, 78.5 and 61.7 wt %, respectively. It was also found that the particle size had no significant effect on LA conversion yield with >3 h reaction time. With delignification using simulated green liquor (Na 2 CO 3 -Na 2 S, 20 wt % total titratable alkali (TTA), 40 wt % sulfidity) at 200 °C for 15 min, lignin removal was in the range of 64.8–91.2 wt %. Removal of both lignin and xylan during delignification increased the glucan contents from 33.0–44.3 of untreated biomass to 61.7–68.4 wt % of treated biomass. Delignified biomass resulted in much lower conversion yield (50.4–56.0 wt %) compared to 60.2–78.5 wt % of untreated biomass. Nonetheless, the concentration of LA in the product was enhanced by a factor of ~1.5 with delignification.

Keywords: biofuel; lignocellulosic biomass; pretreatment; lignin; hydrochloric acid (search for similar items in EconPapers)
JEL-codes: Q Q0 Q4 Q40 Q41 Q42 Q43 Q47 Q48 Q49 (search for similar items in EconPapers)
Date: 2018
References: View references in EconPapers View complete reference list from CitEc
Citations: View citations in EconPapers (1)

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