Study of Conventional Sintered Cu 2 Se Thermoelectric Material

Dongliang Shi, Zhiming Geng and Kwok Ho Lam
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Dongliang Shi: Department of Electrical Engineering, The Hong Kong Polytechnic University, Hong Kong
Zhiming Geng: Department of Electrical Engineering, The Hong Kong Polytechnic University, Hong Kong
Kwok Ho Lam: Department of Electrical Engineering, The Hong Kong Polytechnic University, Hong Kong

Energies, 2019, vol. 12, issue 3, 1-9

Abstract: Lead-free thermoelectric material, copper chalcogenides, have been attracting much interest from many research and industrial applications owing to their high capability of harvesting energy from heat. The state-of-the-art copper chalcogenides are commonly fabricated by the spark plasma sintering (SPS) and hot pressing (HP) techniques. Those methods are still costly and complicated particularly when compared to the conventional solid-state sintering method. Here, we report an easy-to-fabricate lead-free copper(I)-selenium (Cu 2 Se) that was fabricated using the conventional sintering method. The fabrication conditions, including sintering temperature and dwelling time, have been systematically studied to optimize the thermoelectric performance of Cu 2 Se. The optimized zT value for the pure Cu 2 Se was found to be 1.2 for the sample sintered at 1173 K for 2 h. The study shows that Cu 2 Se developed using the simple and low-cost techniques could exhibit comparable thermoelectric performance when compared with those fabricated by the SPS method, which provides an alternative potential technique to synthesize high-performance thermoelectric materials in a cost-effective way for industrialization.

Keywords: thermoelectric material; copper selenide; conventional sintering method (search for similar items in EconPapers)
JEL-codes: Q Q0 Q4 Q40 Q41 Q42 Q43 Q47 Q48 Q49 (search for similar items in EconPapers)
Date: 2019
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