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Perovskite CsPbBr 3 Quantum Dots Prepared Using Discarded Lead–Acid Battery Recycled Waste

Lung-Chien Chen, Ching-Ho Tien, Sin-Liang Ou, Kun-Yi Lee, Jianjun Tian, Zong-Liang Tseng, Hao-Tian Chen, Hao-Chung Kuo and An-Cheng Sun
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Lung-Chien Chen: Department of Electro-Optical Engineering, National Taipei University of Technology, Taipei 10608, Taiwan
Ching-Ho Tien: Department of Electro-Optical Engineering, National Taipei University of Technology, Taipei 10608, Taiwan
Sin-Liang Ou: Bachelor Program for Design and Materials for Medical Equipment and Devices, Da-Yeh University, Changhua 51591, Taiwan
Kun-Yi Lee: Department of Electrical Engineering, China University of Science and Technology, Taipei 11581, Taiwan
Jianjun Tian: Institute of Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China
Zong-Liang Tseng: Department of Electronic Engineering, Ming Chi University of Technology, New Taipei City 24301, Taiwan
Hao-Tian Chen: Graduate Institute of Optomechatronics Engineering, China University of Science and Technology, Taipei 11581, Taiwan
Hao-Chung Kuo: Department of Photonics and Institute of Electro-Optical Engineering, National Chiao Tung University, Hsinchu 30010, Taiwan
An-Cheng Sun: Department of Chemical Engineering and Materials Science, Yuan Ze University, Taoyuan City 32003, Taiwan

Energies, 2019, vol. 12, issue 6, 1-8

Abstract: Perovskite CsPbBr 3 quantum dot (CsPbBr 3 -QD) recovery was performed using lead scrap from lead storage batteries. The perovskite CsPbBr 3 -QD characteristics were analyzed using different PbO/recycled PbO 2 ratios. Scanning electron microscopy (SEM) was used to observe the film surface morphology and cross-section. High-resolution transmission electron microscopy (HRTEM) and X-ray diffraction (XRD) were used to observe the perovskite CsPbBr 3 -QDs’ structural characteristics. A photoluminescence (PL) measurement system was used to analyze the optical properties. The results show that lead scrap from lead–acid batteries as a material for perovskite CsPbBr 3 -QD production can be successfully synthesized. This saves material and also proves that recycling is valuable. The proposed approach is helpful for future material shortages and materials not easily accessible. Although the efficiency is not very high, this process will be purified using recycled lead in the future to achieve higher quantum yield.

Keywords: quantum dots; CsPbBr 3; perovskite; recycled waste lead (search for similar items in EconPapers)
JEL-codes: Q Q0 Q4 Q40 Q41 Q42 Q43 Q47 Q48 Q49 (search for similar items in EconPapers)
Date: 2019
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