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Progress in Catalytic Decomposition and Removal of N 2 O in Fluidized Bed

Miao Miao, Man Zhang, Hao Kong, Tuo Zhou, Xinhua Yang and Hairui Yang
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Miao Miao: State Key Laboratory of Power System and Generation Equipment, Department of Energy and Power Engineering, Tsinghua University, Beijing 100084, China
Man Zhang: State Key Laboratory of Power System and Generation Equipment, Department of Energy and Power Engineering, Tsinghua University, Beijing 100084, China
Hao Kong: State Key Laboratory of Power System and Generation Equipment, Department of Energy and Power Engineering, Tsinghua University, Beijing 100084, China
Tuo Zhou: State Key Laboratory of Power System and Generation Equipment, Department of Energy and Power Engineering, Tsinghua University, Beijing 100084, China
Xinhua Yang: State Key Laboratory of Power System and Generation Equipment, Department of Energy and Power Engineering, Tsinghua University, Beijing 100084, China
Hairui Yang: State Key Laboratory of Power System and Generation Equipment, Department of Energy and Power Engineering, Tsinghua University, Beijing 100084, China

Energies, 2021, vol. 14, issue 19, 1-14

Abstract: As a clean fuel combustion technology, the circulating fluidized bed (CFB) has been developed rapidly in recent years, but one of its disadvantages is high N 2 O emissions. With the implementation of increasingly strict pollution control standards, N 2 O decomposition and removal technologies have become the main focus of current research. This paper reviews the latest research on noble metals, metal oxides, the molecular sieve and other new catalysts and decomposition methods for N 2 O removal. The research methods and functions of catalysts are compared and the existing problems are summarized. The future directions of development in N 2 O decomposition and removal are considered. Noble metals and the molecular sieve show satisfactory activity at relatively low temperatures, but their catalytic efficiency is obviously hindered by O 2 , NO and H 2 O. In addition, high costs and insufficient thermal stability limit their widespread industrial application. The metal oxide catalytic technology, especially oxygen carrier-aided combustion (OCAC), is expected to be the ideal method for N 2 O removal in CFB boilers due to its stability and economical feasibility.

Keywords: CFB; fuel; metal oxide; N 2 O decomposition; OCAC (search for similar items in EconPapers)
JEL-codes: Q Q0 Q4 Q40 Q41 Q42 Q43 Q47 Q48 Q49 (search for similar items in EconPapers)
Date: 2021
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