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A Review on Deactivation and Regeneration of Catalysts for Dimethyl Ether Synthesis

Joanna Sobczak, Izabela Wysocka, Stanisław Murgrabia and Andrzej Rogala
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Joanna Sobczak: Department of Process Engineering and Chemical Technology, Chemical Faculty, Gdańsk University of Technology, Narutowicza 11/12, 80-233 Gdańsk, Poland
Izabela Wysocka: Department of Process Engineering and Chemical Technology, Chemical Faculty, Gdańsk University of Technology, Narutowicza 11/12, 80-233 Gdańsk, Poland
Stanisław Murgrabia: Department of Process Engineering and Chemical Technology, Chemical Faculty, Gdańsk University of Technology, Narutowicza 11/12, 80-233 Gdańsk, Poland
Andrzej Rogala: Department of Process Engineering and Chemical Technology, Chemical Faculty, Gdańsk University of Technology, Narutowicza 11/12, 80-233 Gdańsk, Poland

Energies, 2022, vol. 15, issue 15, 1-39

Abstract: The deactivation of catalysts and their regeneration are two very important challenges that need to be addressed for many industrial processes. The most quoted reasons for the deterioration of dimethyl ether synthesis (DME) concern the sintering and the hydrothermal leaching of copper particles, their migration to acid sites, the partial formation of copper and zinc hydroxycarbonates, the formation of carbon deposits, and surface contamination with undesirable compounds present in syngas. This review summarises recent findings in the field of DME catalyst deactivation and regeneration. The most-used catalysts, their modifications, along with a comparison of the basic parameters, deactivation approaches, and regeneration methods are presented.

Keywords: dimethyl ether; catalysts; deactivation; regeneration (search for similar items in EconPapers)
JEL-codes: Q Q0 Q4 Q40 Q41 Q42 Q43 Q47 Q48 Q49 (search for similar items in EconPapers)
Date: 2022
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