Insight into Class G Wellbore Cement Hydration and Mechanism at 150 °C Using Molecular Dynamics

Rengguang Liu, Yan Li (), Tao Du, Shiming Zhou, Peiqing Lu and Yongliang Wang
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Rengguang Liu: State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development, SINOPEC Research Institute of Petroleum Engineering Co., Ltd., Beijing 102206, China
Yan Li: College of Petroleum Engineering, China University of Petroleum (Beijing), Beijing 102249, China
Tao Du: State Key Laboratory for Geomechanics & Deep Underground Engineering, School of Mechanics and Civil Engineering, China University of Mining and Technology, Xuzhou 221116, China
Shiming Zhou: State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development, SINOPEC Research Institute of Petroleum Engineering Co., Ltd., Beijing 102206, China
Peiqing Lu: State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development, SINOPEC Research Institute of Petroleum Engineering Co., Ltd., Beijing 102206, China
Yongliang Wang: School of Mechanics and Civil Engineering, China University of Mining and Technology (Beijing), Beijing 100083, China

Energies, 2022, vol. 15, issue 16, 1-14

Abstract: Neat well cement experience significant strength retrogression at high temperatures above 110 °C, especially at approximately 150 °C. To reveal the mechanism of performance degradation and guide the preparation of high-performance cement, we investigate the hydration process, mechanical behavior, and fracture process for well cement at the temperature of 150 °C based on molecular dynamics simulations and experiments. From triaxial pressure tests and Brazilian splitting tests, the strength, elastic modulus, and Poisson’s ratio of well cement decrease drastically with temperature increases from 80 °C to 150 °C. According to XRD, TG/DTG/DSC, and SEM, the hydration degree is insufficient, and larger pores exist in the microstructures. As the main binding phase of well cement, the mechanism of calcium silicate hydrates (C-S-H) influenced by curing temperatures is investigated through molecular dynamics simulations. C-S-H with calcium/silicon ratios (C/S) of 1.1 and 1.8 are simulated in the aqueous and solid states to investigate precipitation and mechanical behaviors. By reducing the C/S ratio to 1.1, the strength rebounds to a certain extent, and the adequacy of the hydration degree improved. It is found from the polymerization process that the increasing temperature promotes the polymerization rate, which is higher with C/S = 1.8 than that of 1.1. However, an increase in the C/S ratio will lead to a decrease in bridging oxygen content, thus a lower polymerization degree. The fracture simulations of C-S-H gels at different temperatures indicate that the failure of the C-S-H structure is mainly attributed to the disassembling of the calcium oxygen layers. With a higher temperature, there are fewer Ca-O bonds breaking, thus less strain energy consumed, resulting in worse performance. The elasticity of C-S-H, including Young’s and shear moduli, also exhibits certain degradations at a higher temperature. The elastic behavior of C-S-H with a low C/S ratio is generally higher than the high C/S.

Keywords: molecular dynamics; high temperature; hydration process; mechanical properties; fracture behavior; wellbore cement; well integrity (search for similar items in EconPapers)
JEL-codes: Q Q0 Q4 Q40 Q41 Q42 Q43 Q47 Q48 Q49 (search for similar items in EconPapers)
Date: 2022
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