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A Brief Review of the Supercritical Antisolvent (SAS) Technique for the Preparation of Nanocatalysts to Be Used in Biodiesel Production

Samuel Santos, Jaime Puna and João Gomes ()
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Samuel Santos: CERENA—Center for Natural Resources and Instituto Superior Técnico, University of Lisbon, Av. Rovisco Pais, 1, 1049-001 Lisboa, Portugal
Jaime Puna: CERENA—Center for Natural Resources and Instituto Superior Técnico, University of Lisbon, Av. Rovisco Pais, 1, 1049-001 Lisboa, Portugal
João Gomes: CERENA—Center for Natural Resources and Instituto Superior Técnico, University of Lisbon, Av. Rovisco Pais, 1, 1049-001 Lisboa, Portugal

Energies, 2022, vol. 15, issue 24, 1-7

Abstract: In an era where sustainability is becoming the main driving force for research and development, supercritical fluids-based techniques are presented as a very efficient alternative technology to conventional extraction, purification, and recrystallization processes. Supercritical antisolvent (SAS) precipitation is a novel technique that can replace liquid antisolvent precipitation techniques. Additionally, through the optimization of precipitation operating conditions, morphology, particle size, and particle size distribution of nanoparticles can be controlled. As an antisolvent, supercritical carbon dioxide (scCO 2 ) is far more sustainable than its conventional liquid counterparts; not only does it have a critical point (304 K and 73.8 bar) on its phase diagram that allows for the precipitation processes to be developed so close to room temperature, but also its recovery and, consequently, the precipitated solute purification stage is considerably simpler. This technique can be used efficiently for preparing nanocatalysts to be used in biodiesel production processes.

Keywords: supercritical antisolvent precipitation; carbon dioxide; supercritical CO 2; nanoparticles; biodiesel catalysts (search for similar items in EconPapers)
JEL-codes: Q Q0 Q4 Q40 Q41 Q42 Q43 Q47 Q48 Q49 (search for similar items in EconPapers)
Date: 2022
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