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Potential of NiO x /Nickel Silicide/n + Poly-Si Contact for Perovskite/TOPCon Tandem Solar Cells

Jiryang Kim, Dowon Pyun, Dongjin Choi, Seok-Hyun Jeong, Changhyun Lee, Jiyeon Hyun, Ha Eun Lee, Sang-Won Lee, Hoyoung Song, Solhee Lee, Donghwan Kim, Yoonmook Kang and Hae-Seok Lee
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Jiryang Kim: Graduate School of Energy and Environment (KU-KIST Green School), Korea University, 145 Anam-ro, Seongbuk-gu, Seoul 02841, Korea
Dowon Pyun: Department of Materials Science and Engineering, Korea University, 145 Anam-ro, Seongbuk-gu, Seoul 02841, Korea
Dongjin Choi: Department of Materials Science and Engineering, Korea University, 145 Anam-ro, Seongbuk-gu, Seoul 02841, Korea
Seok-Hyun Jeong: Department of Materials Science and Engineering, Korea University, 145 Anam-ro, Seongbuk-gu, Seoul 02841, Korea
Changhyun Lee: Department of Materials Science and Engineering, Korea University, 145 Anam-ro, Seongbuk-gu, Seoul 02841, Korea
Jiyeon Hyun: Department of Materials Science and Engineering, Korea University, 145 Anam-ro, Seongbuk-gu, Seoul 02841, Korea
Ha Eun Lee: Department of Materials Science and Engineering, Korea University, 145 Anam-ro, Seongbuk-gu, Seoul 02841, Korea
Sang-Won Lee: Department of Materials Science and Engineering, Korea University, 145 Anam-ro, Seongbuk-gu, Seoul 02841, Korea
Hoyoung Song: Department of Materials Science and Engineering, Korea University, 145 Anam-ro, Seongbuk-gu, Seoul 02841, Korea
Solhee Lee: Department of Materials Science and Engineering, Korea University, 145 Anam-ro, Seongbuk-gu, Seoul 02841, Korea
Donghwan Kim: Department of Materials Science and Engineering, Korea University, 145 Anam-ro, Seongbuk-gu, Seoul 02841, Korea
Yoonmook Kang: Graduate School of Energy and Environment (KU-KIST Green School), Korea University, 145 Anam-ro, Seongbuk-gu, Seoul 02841, Korea
Hae-Seok Lee: Graduate School of Energy and Environment (KU-KIST Green School), Korea University, 145 Anam-ro, Seongbuk-gu, Seoul 02841, Korea

Energies, 2022, vol. 15, issue 3, 1-11

Abstract: In this work, nickel silicide was applied to tandem solar cells as an interlayer. By the process of thermal evaporation, a layer of NiO x , hole transport layer (HTL) was deposited on n + poly-Si layer directly. Nickel silicide was simultaneously formed by nickel diffusion from NiO x to n + poly-Si layer during the deposition and annealing process. The I–V characteristics of NiO x /n + poly-Si contact with nickel silicide showed ohmic contact and low contact resistivity. This structure is expected to be more advantageous for electrical connection between perovskite top cell and TOPCon bottom cell compared to the NiO x /TCO/n + poly-Si structure showing Schottky contact. Furthermore, nickel silicide and Ni-deficient NiO x thin film formed by diffusion of nickel can improve the fill factor of the two sub cells. These results imply the potential of a NiO x /nickel silicide/n + poly-Si structure as a perovskite/silicon tandem solar cell interlayer.

Keywords: perovskite/silicon tandem solar cells; nickel silicide; NiO x /n + poly-Si contact; X-ray photoelectron spectroscopy (search for similar items in EconPapers)
JEL-codes: Q Q0 Q4 Q40 Q41 Q42 Q43 Q47 Q48 Q49 (search for similar items in EconPapers)
Date: 2022
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