Coprecipitation Synthesis and Impedance Studies on Electrode Interface Characteristics of 0.5Li 2 MnO 3 ·0.5Li(Ni 0.44 Mn 0.44 Co 0.12 )O 2 Cathode Material

Xing Zhao, Peng Wang, Yan Wang, Peipei Chao and Honglei Dong ()
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Xing Zhao: China Automotive Engineering Research Institute Co., Ltd., Chongqing 401122, China
Peng Wang: China Automotive Engineering Research Institute Co., Ltd., Chongqing 401122, China
Yan Wang: Defective Product Administrative Center, State Administration for Market Regulation, Beijing 100088, China
Peipei Chao: China Automotive Engineering Research Institute Co., Ltd., Chongqing 401122, China
Honglei Dong: Defective Product Administrative Center, State Administration for Market Regulation, Beijing 100088, China

Energies, 2023, vol. 16, issue 16, 1-16

Abstract: The nanoscale 0.5Li 2 MnO 3 ·0.5Li(Ni 0.44 Mn 0.44 Co 0.12 )O 2 Li-manganese-rich electrode material was synthesized by the co-precipitate method, and its electrochemical properties were systematically analyzed, especially the electrochemical impedance spectroscopy. The failure of the electrode interface and the structural transformation of the material at high potential are the main reasons for the deterioration of the Li-manganese-rich electrode, and high temperatures accelerate the deterioration. Based on the systematic analysis of the induced reactance change with electrode polarization potential, it is found that the induced reactance of a Li-manganese-rich electrode is not only related to the degree of delithiation/lithiation but also has a great relationship with the performance of the electrode/electrolyte interface. This conclusion is beneficial for the manufacturing of battery failure analysis by providing a theoretical basis for guidance.

Keywords: Li-manganese-rich electrode; electrochemical impedance spectroscopy (EIS); induced reactance; electrode/electrolyte interface (search for similar items in EconPapers)
JEL-codes: Q Q0 Q4 Q40 Q41 Q42 Q43 Q47 Q48 Q49 (search for similar items in EconPapers)
Date: 2023
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