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The Influence of Hydrogen on Structural and Magnetic Transformations in R Mn 2 H x Hydrides with Laves Phase C15 and C14 Structures—A Review

Andrzej Budziak () and Joanna Szafraniec
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Andrzej Budziak: Faculty of Energy and Fuels, AGH University of Science and Technology, al. Mickiewicza 30, 30-059 Kraków, Poland
Joanna Szafraniec: Faculty of Energy and Fuels, AGH University of Science and Technology, al. Mickiewicza 30, 30-059 Kraków, Poland

Energies, 2023, vol. 16, issue 21, 1-25

Abstract: Laves phases crystallize in simple structures and are very common intermetallic phases that can form from combinations of elements throughout the periodic table, giving a huge number of known examples. A special feature of AB2 or AB5 phases is the ability to absorb hydrogen. This study attempts to collect, systematize and summarize the knowledge about R Mn 2 H x ( R : Tb, Gd, Ho, Dy, Er, Sm, Nd and Y) hydrides available in the literature that is mainly related to structural and magnetic transformations. Due to the enormous wealth of data, the analysis focused on hydrides with x < 4.5 H/f.u., i.e., hydrides obtained at relatively low pressure (less than a few bars). The hydrides obtained in this way can be treated as potential hydrogen stores, which undoubtedly accounts for their current attractiveness.

Keywords: metal hydrides; Laves phases; hydrogen storage; X-ray diffraction; magnetic measurements (search for similar items in EconPapers)
JEL-codes: Q Q0 Q4 Q40 Q41 Q42 Q43 Q47 Q48 Q49 (search for similar items in EconPapers)
Date: 2023
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