Experimental Study on SiO 2 Nanoparticles-Assisted Alpha-Olefin Sulfonate Sodium (AOS) and Hydrolyzed Polyacrylamide (HPAM) Synergistically Enhanced Oil Recovery
Jiani Hu,
Meilong Fu (),
Yuxia Zhou,
Fei Wu and
Minxuan Li
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Jiani Hu: Hubei Key Laboratory of Oil and Gas Drilling and Production Engineering, College of Petroleum Engineering, Yangtze University, Wuhan 430100, China
Meilong Fu: Hubei Key Laboratory of Oil and Gas Drilling and Production Engineering, College of Petroleum Engineering, Yangtze University, Wuhan 430100, China
Yuxia Zhou: CNOOC China Limited Hainan Branch, Haikou 570100, China
Fei Wu: Drilling and Production Technology Research Institute, PetroChina Qinghai Oilfield Company, Jiuquan 736202, China
Minxuan Li: CNOOC China Limited Hainan Branch, Haikou 570100, China
Energies, 2023, vol. 16, issue 22, 1-13
Abstract:
The purpose of this study is to investigate the use of SiO 2 nanoparticles in assisting with surfactants and polymers for tertiary oil recovery, with the aim of enhancing oil recovery. The article characterizes the performance of SiO 2 nanoparticles, including particle size, dispersion stability, and zeta potential, evaluates the synergistic effects of nanoparticles with alpha-olefin sulfonate sodium (AOS) surfactants and hydrolyzed polyacrylamide (HPAM) on reducing interfacial tension and altering wettability, and conducts core flooding experiments in rock cores with varying permeabilities. The findings demonstrate that the particle size decreased from 191 nm to 125 nm upon the addition of SiO 2 nanoparticles to AOS surfactant, but increased to 389 nm upon the addition of SiO 2 nanoparticles to HPAM. The dispersibility experiment showed that the SiO 2 nanoparticle solution did not precipitate over 10 days. After adding 0.05% SiO 2 nanoparticles to AOS surfactant, the zeta potential was −40.2 mV, while adding 0.05% SiO 2 nanoparticles to 0.1% HPAM resulted in a decrease in the zeta potential to −25.03. The addition of SiO 2 nanoparticles to AOS surfactant further reduced the IFT value to 0.19 mN/m, altering the rock wettability from oil-wet to strongly water-wet, with the contact angle decreasing from 110° to 18°. In low-permeability rock core oil displacement experiments, the use of AOS surfactants and HPAM for enhanced oil recovery increased the recovery rate by 24.5% over water flooding. The recovery rate increased by 21.6% over water flooding in low-permeability rock core experiments after SiO 2 nanoparticles were added and surfactants and polymers were utilized for oil displacement. This is because the nanoparticles blocked small pore throats, resulting in increased resistance and hindered free fluid flow. The main causes of this plugging are mutual interference and mechanical entrapment, which cause the pressure differential to rise quickly. In high-permeability rock core oil displacement experiments, the use of AOS surfactants and HPAM for oil recovery increased the recovery rate by 34.6% over water flooding. Additionally, the recovery rate increased by 39.4% over water flooding with the addition of SiO 2 nanoparticles and the use of AOS surfactants and HPAM for oil displacement. Because SiO 2 nanoparticles create wedge-shaped structures inside highly permeable rock cores, they create structural separation pressure, which drives crude oil forward and aids in diffusion. This results in a comparatively small increase in pressure differential. Simultaneously, the nanoparticles change the rock surfaces’ wettability, which lowers the amount of crude oil that adsorbs and improves oil recovery.
Keywords: SiO 2 nanoparticles; enhanced oil recovery; performance characterization; oil displacement experiment (search for similar items in EconPapers)
JEL-codes: Q Q0 Q4 Q40 Q41 Q42 Q43 Q47 Q48 Q49 (search for similar items in EconPapers)
Date: 2023
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