A Study on Elemental Sulfur Equilibrium Content in Mixtures of Methane, Carbon Dioxide, and Hydrogen Sulfide under Conditions of Natural Gas Pipeline Transmission

Gang Liu (), Mengqi Hao, Shishui Fan and Changjun Li
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Gang Liu: College of Safety Engineering, Chongqing University of Science & Technology, Chongqing 401331, China
Mengqi Hao: College of Safety Engineering, Chongqing University of Science & Technology, Chongqing 401331, China
Shishui Fan: College of Safety Engineering, Chongqing University of Science & Technology, Chongqing 401331, China
Changjun Li: CNPC Key Laboratory of Oil & Gas Storage and Transportation, School of Petroleum Engineering, Southwest Petroleum University, Chengdu 610500, China

Energies, 2023, vol. 16, issue 5, 1-26

Abstract: The effect of gathering pipeline pressure, temperature, and key components on the solubility of monomeric sulfur in high-sulfur-content natural gas is directly related to the prediction and prevention of sulfur deposition in surface gathering pipelines. Based on our previous study on a prediction model of sulfur solubility in gas with a new formula for the binary interaction coefficient between sulfur and H 2 S, a new gas–solid thermodynamic phase equilibrium solubility prediction model for monomeric sulfur in high-sulfur-content natural gas was improved based on the gas–solid phase equilibrium principle considering both physical and chemical solution mechanisms. Two new expressions for binary interaction coefficients between sulfur and CO 2 and CH 4 , considering both temperature and solvent density, are proposed in this new solubility prediction model. In this paper, the main factors, such as the gathering pipeline pressure, gathering pipeline temperature, H 2 S, and CO 2 , affecting the solubility law of elemental sulfur in high-sulfur-content natural gas are investigated. The results show that the total solubility of elemental sulfur in high-sulfur-bearing natural gas tends to decrease with an increase in the gathering temperature, in which the increase in temperature promotes physical solution, and the physical solution mechanism prevails. Conversely, chemical solution is promoted, and the chemical solution mechanism prevails. With an increase in the gathering pressure, the total solubility of elemental sulfur in high-sulfur-content gas tends to increase, where the physical solubility decreases slightly at first and then increases continuously, with a pressure inflection point of about 2.0 MPa, and the pressure increase has a significant promoting effect on the chemical solubility of elemental sulfur. The increase in the H 2 S concentration promotes the solution of elemental sulfur in the gas phase in general and significantly promotes the chemical solution of elemental sulfur. The effect on elemental sulfur solubility can be neglected when the molar concentration of CO 2 in the gas phase does not exceed 10%.

Keywords: high-sulfur-content natural gas; pipeline; sulfur deposition; thermodynamic model; solution mechanism (search for similar items in EconPapers)
JEL-codes: Q Q0 Q4 Q40 Q41 Q42 Q43 Q47 Q48 Q49 (search for similar items in EconPapers)
Date: 2023
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