Aspects Regarding the Modelling and Optimization of the Transesterification Process through Temperature Control of the Chemical Reactor

Ruxandra-Cristina Stanescu, Cristian-Ioan Leahu () and Adrian Soica
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Ruxandra-Cristina Stanescu: Department of Automotive and Transport Engineering, Transilvania University of Brasov, 500036 Brasov, Romania
Cristian-Ioan Leahu: Department of Automotive and Transport Engineering, Transilvania University of Brasov, 500036 Brasov, Romania
Adrian Soica: Department of Automotive and Transport Engineering, Transilvania University of Brasov, 500036 Brasov, Romania

Energies, 2023, vol. 16, issue 6, 1-17

Abstract: Currently, biofuels represent a solution for the European Union in the transportation sector in order to reduce the greenhouse gas (GHG) emissions and the dependency of fossil fuels. Biodiesel from vegetable oils is a solution for countries with low GDP per capita to strengthen the internal agriculture, provide jobs, and reduce the use of fossil fuels. In this study, we model and simulate a temperature regulator designed for the biodiesel transesterification process in a discontinuous batch reactor, using methanol and a homogenous basic catalyst. The simulation was based on the kinetical model of the transesterification reaction and the mathematical model of the reactor. We considered molar ratios of alcohol/oil of 6:1 and 9:1, respectively, to shift the reaction equilibrium towards the production of fatty acid methyl esters. In the design of the simulation, the methanol boiling point was considered a restriction, therefore, temperatures below 65 °C were imposed. The results demonstrate that the increase in temperature results in a decrease in the reaction time and a higher yield, especially for the 6:1 molar ratio reaction, and that the optimum temperature for the batch reactor is of 60 °C. Automatic control improves the performance and costs of production.

Keywords: biofuel; transesterification; reactor; temperature control (search for similar items in EconPapers)
JEL-codes: Q Q0 Q4 Q40 Q41 Q42 Q43 Q47 Q48 Q49 (search for similar items in EconPapers)
Date: 2023
References: View references in EconPapers View complete reference list from CitEc
Citations: View citations in EconPapers (1)

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