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Experimental Investigation of Enhanced Oil Recovery Mechanism of CO 2 Huff and Puff in Saturated Heavy Oil Reservoirs

Xiaorong Shi, Qian Wang, Ke Zhao, Yongbin Wu (), Hong Dong, Jipeng Zhang and Ye Yao
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Xiaorong Shi: Research Institute of Petroleum Exploration and Development, Xinjiang Oilfield Company, PetroChina, Karamay 834000, China
Qian Wang: Research Institute of Petroleum Exploration and Development, PetroChina, Beijing 100083, China
Ke Zhao: Heavy Oil Recovery Branch of Xinjiang Oilfield Company, PetroChina, Karamay 834000, China
Yongbin Wu: Research Institute of Petroleum Exploration and Development, PetroChina, Beijing 100083, China
Hong Dong: Research Institute of Petroleum Exploration and Development, Xinjiang Oilfield Company, PetroChina, Karamay 834000, China
Jipeng Zhang: School of Energy Resources, China University of Geosciences, Beijing 100083, China
Ye Yao: School of Accounting, Shanghai Lixin Accounting and Finance College, Shanghai 201600, China

Energies, 2024, vol. 17, issue 24, 1-16

Abstract: Due to the significance of carbon utilization and storage, CO 2 huff and puff is increasingly receiving attention. However, the mechanisms and effects of CO 2 huff and puff extraction in medium to deep saturated heavy oil reservoirs remain unclear. Therefore, in this study, by targeting the medium to deep saturated heavy oil reservoirs in the block Xia of the Xinjiang oil field, measurements of physical properties were conducted through PVT analysis and viscosity measurement to explore the dissolution and diffusion characteristics of CO 2 -degassed and CO 2 -saturated oil systems. Multiple sets of physical simulation of CO 2 huff and puff in medium to deep saturated heavy oil reservoirs were conducted using a one-dimensional core holder to evaluate the EOR mechanism of CO 2 huff and puff. The results demonstrate that the solubility of CO 2 in degassed crude oil is linearly correlated with pressure. Higher pressure effectively increases the solubility of CO 2 , reaching 49.1 m 3 /m 3 at a saturation pressure of 10.0 MPa, thus facilitating oil expansion and viscosity reduction. Meanwhile, crude oil saturated with CH 4 still retains the capacity to further dissolve additional CO 2 , reaching 24.5 m 3 /m 3 of incremental CO 2 solubilization at 10.0 MPa, and the hybrid effect of CO 2 and CH 4 reduces oil viscosity to 1161 mPa·s, which is slightly lower than the pure CO 2 dissolution case. Temperature increases suppress solubility but promote molecular diffusion, allowing CH 4 and CO 2 to maintain a certain solubility at high temperatures. In terms of dynamic dissolution and diffusion, the initial CO 2 dissolution rate is high, reaching 0.009 m 3 /(m 3 ·min), the mid-term dissolution rate stabilizes at approximately 0.002 m 3 /(m 3 ·min), and the dissolution capability significantly decreases later on. CO 2 exhibits high molecular diffusion capability in gas-saturated crude oil, with a diffusion coefficient of 8.62 × 10 −7 m 2 /s. For CO 2 huff and puff, oil production is positively correlated with the CO 2 injection rate and the cycle injection volume; it initially increases with the extension of the soak time but eventually decreases. Therefore, the optimal injection speed, injection volume, and soak time should be determined in conjunction with reservoir characteristics. During the huff and puff process, the bottom hole pressure should be higher than the bubble point pressure of the crude oil to prevent gas escape. Moreover, as the huff and puff cycles increase, the content of saturates in the oil rises, while those of aromatic, resin, and asphaltene decrease, leading to a gradual deterioration of the huff and puff effect. This study provides a comprehensive reference method and conclusions for studying the fluid property changes and enhanced recovery mechanisms in medium to deep heavy oil reservoirs with CO 2 huff and puff.

Keywords: medium to deep saturated heavy oil; CO 2 huff and puff; dissolution and diffusion; EOR mechanism (search for similar items in EconPapers)
JEL-codes: Q Q0 Q4 Q40 Q41 Q42 Q43 Q47 Q48 Q49 (search for similar items in EconPapers)
Date: 2024
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