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Insight into the Microscopic Interactions Among Steam, Non-Condensable Gases, and Heavy Oil in Steam and Gas Push Processes: A Molecular Dynamics Simulation Study

Jiuning Zhou, Xiyan Wang, Xiaofei Sun () and Zifei Fan
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Jiuning Zhou: Research Institute of Petroleum Exploration and Development, CNPC, Beijing 100083, China
Xiyan Wang: School of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, China
Xiaofei Sun: School of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, China
Zifei Fan: Research Institute of Petroleum Exploration and Development, CNPC, Beijing 100083, China

Energies, 2024, vol. 18, issue 1, 1-22

Abstract: The SAGP (steam and gas push) process is an effective enhanced oil recovery (EOR) method for heavy oil reservoirs. Understanding the microscopic interactions among steam, non-condensable gasses (NCGs), and heavy oil under reservoir conditions in SAGP processes is important for their EOR applications. In this study, molecular simulations were performed to investigate the microscopic interactions among steam, NCG, and heavy oil under reservoir conditions in SAGP processes. In addition, the microscopic EOR mechanisms during SAGP processes and the effects of operational parameters (NCG type, NCG–steam mole ratio, temperature, and pressure) were discussed. The results show that the diffusion and dissolution of CH 4 molecules and the extraction of steam molecules cause the molecules of saturates with light molecular weights in the oil globules to stretch and gradually detach from one another, resulting in the swelling of heavy oil. Compared with N 2 , CH 4 has a stronger ability to diffuse and dissolve in heavy oil, swell the heavy oil, and reduce the density and viscosity of heavy oil. For this reason, compared with cases where N 2 is used, SAGP processes perform better when CH 4 is used, indicating that CH 4 can be used as the injected NCG in the SAGP process to improve heavy oil recovery. As the NCG–steam mole ratio and injection pressure increase, the diffusion and solubility abilities of CH 4 in heavy oil increase, enabling CH 4 to perform better in swelling the heavy oil and reducing the density and viscosity of heavy oil. Hence, increasing the NCG–steam mole ratio and injection pressure is helpful in improving the performance of SAGP processes in heavy oil reservoirs. However, the NCG–steam mole ratio and injection pressure should be reasonably determined based on actual field conditions because excessively high NCG–steam mole ratios and injection pressures lead to higher operation costs. Increasing the temperature is favorable for increasing the diffusion coefficient of CH 4 in heavy oil, swelling heavy oil, and reducing the oil density and viscosity. However, high temperatures can result in intensified thermal motion of CH 4 molecules, reduce the interaction energy between CH 4 molecules and heavy oil molecules, and increase the difference in the Hildebrand solubility parameter between heavy oil and CH 4 –steam mixtures, which is unfavorable for the dissolution of CH 4 in heavy oil. This study can help readers deeply understand the microscopic interactions among steam, NCG, and heavy oil under reservoir conditions in SAGP processes and its results can provide valuable information for the actual application of SAGP processes in enhancing heavy oil recovery.

Keywords: non-condensable gases; heavy oil; steam; steam and gas push; molecular dynamics simulations (search for similar items in EconPapers)
JEL-codes: Q Q0 Q4 Q40 Q41 Q42 Q43 Q47 Q48 Q49 (search for similar items in EconPapers)
Date: 2024
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