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A Review on the Overall Performance of Metal Hydride-Based Hydrogen Storage Systems

Puchanee Larpruenrudee, Nick S. Bennett, Zhen Luo, M. J. Hossain, Nawshad Haque, Emilie Sauret, Robert Fitch and Mohammad S. Islam ()
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Puchanee Larpruenrudee: School of Mechanical and Mechatronic Engineering, University of Technology Sydney, Ultimo, NSW 2007, Australia
Nick S. Bennett: School of Mechanical and Mechatronic Engineering, University of Technology Sydney, Ultimo, NSW 2007, Australia
Zhen Luo: School of Mechanical and Mechatronic Engineering, University of Technology Sydney, Ultimo, NSW 2007, Australia
M. J. Hossain: School of Electrical and Data Engineering, University of Technology Sydney, 15 Broadway, Ultimo, NSW 2007, Australia
Nawshad Haque: CSIRO Mineral Resources, Clayton South, Melbourne, VIC 3169, Australia
Emilie Sauret: School of Mechanical, Medical and Process Engineering, Faculty of Engineering, Queensland University of Technology, Brisbane, QLD 4000, Australia
Robert Fitch: School of Mechanical and Mechatronic Engineering, University of Technology Sydney, Ultimo, NSW 2007, Australia
Mohammad S. Islam: School of Mechanical and Mechatronic Engineering, University of Technology Sydney, Ultimo, NSW 2007, Australia

Energies, 2025, vol. 18, issue 5, 1-50

Abstract: Metal hydride-based hydrogen storage (MHHS) has been used for several purposes, including mobile and stationary applications. In general, the overall MHHS performance for both applications depends on three main factors, which are the appropriate selection of metal hydride material uses, design configurations of the MHHS based on the heat exchanger, and overall operating conditions. However, there are different specific requirements for the two applications. The weight of the overall MHHS is the key requirement for mobile applications, while hydrogen storage capacity is the key requirement for stationary applications. Based on these requirements, several techniques have been recently used to enhance MHHS performance by mostly considering the faster hydrogen absorption/desorption reaction. Considering metal hydride (MH) materials, their low thermal conductivity significantly impacts the hydrogen absorption/desorption reaction. For this purpose, a comprehensive understanding of these three main factors and the hydrogen absorption/desorption reaction is critical and it should be up to date to obtain the suitable MHHS performance for all related applications. Therefore, this article reviews the key techniques, which have recently been applied for the enhancement of MHHS performance. In the review, it is demonstrated that the design and layout of the heat exchanger greatly affect the performance of the internal heat exchanger. The initial temperature of the heat transfer fluid and hydrogen supply pressure are the main parameters to increase the hydrogen sorption rate and specific heating power. The higher supply pressure results in the improvement in specific heating power. For the metal hydride material selection under the consideration of mobile applications and stationary applications, it is important to strike trade-offs between hydrogen storage capacity, weight, material cost, and effective thermal conductivity.

Keywords: metal hydride; hydrogen storage; hydrogen absorption and desorption; thermal design; heat transfer enhancement; heat exchanger (search for similar items in EconPapers)
JEL-codes: Q Q0 Q4 Q40 Q41 Q42 Q43 Q47 Q48 Q49 (search for similar items in EconPapers)
Date: 2025
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