Modeling of Proton-Conducting Solid Oxide Fuel Cells Fueled with Syngas
Meng Ni,
Zongping Shao and
Kwong Yu Chan
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Meng Ni: Department of Building and Real Estate, the Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong, China
Zongping Shao: State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry & Chemical Engineering, Nanjing University of Technology, No. 5 Xin Mofan Road, Nanjing 210009, China
Kwong Yu Chan: Department of Chemistry, the University of Hong Kong, Pokfulam Road, Hong Kong, China
Energies, 2014, vol. 7, issue 7, 1-16
Abstract:
Solid oxide fuel cells (SOFCs) with proton conducting electrolyte (H-SOFCs) are promising power sources for stationary applications. Compared with other types of fuel cells, one distinct feature of SOFC is their fuel flexibility. In this study, a 2D model is developed to investigate the transport and reaction in an H-SOFC fueled with syngas, which can be produced from conventional natural gas or renewable biomass. The model fully considers the fluid flow, mass transfer, heat transfer and reactions in the H-SOFC. Parametric studies are conducted to examine the physical and chemical processes in H-SOFC with a focus on how the operating parameters affect the H-SOFC performance. It is found that the presence of CO dilutes the concentration of H 2 , thus decreasing the H-SOFC performance. With typical syngas fuel, adding H 2 O cannot enhance the performance of the H-SOFC, although water gas shift reaction can facilitate H 2 production.
Keywords: proton-conducting solid oxide fuel cells; mathematical modeling; coupled transport and reaction; syngas; water gas shift reaction; computational fluid dynamics; electrochemistry (search for similar items in EconPapers)
JEL-codes: Q Q0 Q4 Q40 Q41 Q42 Q43 Q47 Q48 Q49 (search for similar items in EconPapers)
Date: 2014
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Citations: View citations in EconPapers (2)
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Persistent link: https://EconPapers.repec.org/RePEc:gam:jeners:v:7:y:2014:i:7:p:4381-4396:d:37998
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