Characteristics of Authigenic Minerals around the Sulfate-Methane Transition Zone in the Methane-Rich Sediments of the Northern South China Sea: Inorganic Geochemical Evidence

Daidai Wu, Tiantian Sun, Rui Xie, Mengdi Pan, Xuegang Chen, Ying Ye, Lihua Liu and Nengyou Wu
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Daidai Wu: Key Laboratory of Gas Hydrate, Guangzhou Institute of Energy Conversion, Chinese Academy of sciences, Guangzhou 510640, China
Tiantian Sun: Key Laboratory of Gas Hydrate, Guangzhou Institute of Energy Conversion, Chinese Academy of sciences, Guangzhou 510640, China
Rui Xie: Key Laboratory of Gas Hydrate, Guangzhou Institute of Energy Conversion, Chinese Academy of sciences, Guangzhou 510640, China
Mengdi Pan: Key Laboratory of Gas Hydrate, Guangzhou Institute of Energy Conversion, Chinese Academy of sciences, Guangzhou 510640, China
Xuegang Chen: Ocean College, Zhejiang University, Zhoushan 316021, China
Ying Ye: Ocean College, Zhejiang University, Zhoushan 316021, China
Lihua Liu: Key Laboratory of Gas Hydrate, Guangzhou Institute of Energy Conversion, Chinese Academy of sciences, Guangzhou 510640, China
Nengyou Wu: Laboratory of Marine Mineral Resources, Pilot National Laboratory for Marine Sciences and Technology (Qingdao), Qingdao 266071, China

IJERPH, 2019, vol. 16, issue 13, 1-18

Abstract: Sediments at marine cold seep areas provide potential archives of past fluid flow, which allow insights into the evolution of past methane seepage activities. However, signals for anaerobic oxidation of methane (AOM) might be obscured in bulk sediments in cold-seep settings due to several factors, especially flood and turbidite deposition. Comprehensive inorganic data were gathered in this study to explore the availability of related records at cold seeps and to provide insights into the evolution of past methane seepage activities. Sediments collected from the site 973-4 in the Taixinan Basin on the northern slope of the South China Sea were characterized in terms of total carbon and sulfur, δ 13 C values of total organic carbon (δ 13 C TIC ), δ 34 S values of chromium reducible sulfur (δ 34 S CRS ), and foraminiferal oxygen and carbon isotopes. The results confirmed a strong correlation between formation of authigenic minerals and AOM. Moreover, the 34 S enrichments and abundant chromium reducible sulfur (CRS) contents in the authigenic sulfides in the sulfate–methane transition zone (SMTZ) within 619–900 cm below seafloor (cmbsf) reflected past high methane fluxes supported by constant methane seepages. Lithological distribution and AMS (Accelerator Mass Spectra) 14 C dating of planktonic foraminifera show that the turbidite (~35.14 ka) was related to a foraminifera-rich interval (Unit II: 440-619 cmbsf) and increased carbonate productivity during the last glacial maximum (LGM). Enrichment of Mo and U was observed accompanied by low contents of nutrient metals (Al, Ti, V, Ni, Fe, Mn, and Cu) in Unit II. The foraminifera-rich interval (Unit II) of cold seep sediments was probably linked to the phenomenon of inconsecutive sedimentary sequence due to the turbidites, which resulted in the lack of Fe, Mn, and Ba enrichment. There is no U enrichment but only Mo enrichment within Unit III, which might be related to H 2 S produced by AOM during the methane seepages. Based on the above results, it can be speculated that this area has experienced multiple-episodes of methane seep events. Further exploration of AOM should focus on the risks of rapid deposition, especially the impact of turbidity current on sediments.

Keywords: authigenic minerals; anaerobic oxidation of methane; chromium reducible sulfur; methane seepage; South China Sea (search for similar items in EconPapers)
JEL-codes: I I1 I3 Q Q5 (search for similar items in EconPapers)
Date: 2019
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