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Effect of Surface Treatment by O 3 and Chemical Activation by Alkali Metal on the Performance of ACFs on Adsorption and Desorption of BTX Gases

Jung Hee Jang and Gi Bo Han
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Jung Hee Jang: Department of Applied Environmental Science, Graduate School, Kyung Hee University, Yongin-si, Gyeonggi-do 17104, Korea
Gi Bo Han: Plant Engineering Center, Institute for Advanced Engineering, 633-2 Goan-ri, Baegam-myon, Cheoin-gu, Yongin-si, Gyeonggi-do 17528, Korea

IJERPH, 2020, vol. 17, issue 15, 1-12

Abstract: In order to investigate the adsorption characteristics of activated carbon fibers (ACFs) with improved surface morphologies towards volatile organic compounds (VOCs), a commercial low-grade ACF was surface modified by successive surface treatment (ST) and chemical activation (CA) process. O 3 was used as an ST agent for the formation of oxygen-containing functional groups on the carbon matrix of ACFs. CA was carried out after ST, using a KOH solution. After the successive ST-CA process, Brunauer-Emmett-Teller (BET) surface area and average pore diameter of ACFs were increased from 1483 m 2 /g to 2743 m 2 /g and enlarged from 1.931 nm to 2.512 nm, respectively. The successive ST-CA process also resulted in the adsorption capacities of benzene, toluene, and xylene of the ACFs to increase from 0.22 g −Ben. /g −ACFs , 0.18 g −Tol. /g −ACFs , and 0.19 g −Xyl /g −ACFs up to 0.37 g −Ben. /g −ACFs , 0.35 g −Tol. /g −ACFs , and 0.38 g −Xyl /g −ACFs , respectively.

Keywords: activated carbon fiber; surface treatment; chemical activation; BTX gas adsorption; textural properties; IAQ (search for similar items in EconPapers)
JEL-codes: I I1 I3 Q Q5 (search for similar items in EconPapers)
Date: 2020
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