Modeling Porosity Distribution Strategies in PEM Water Electrolyzers: A Comparative Analytical and Numerical Study

Ali Bayat, Prodip K. Das and Suvash C. Saha ()
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Ali Bayat: School of Mechanical and Mechatronic Engineering, University of Technology Sydney, Sydney, NSW 2007, Australia
Prodip K. Das: School of Engineering, The University of Edinburgh, Edinburgh EH9 3FB, UK
Suvash C. Saha: School of Mechanical and Mechatronic Engineering, University of Technology Sydney, Sydney, NSW 2007, Australia

Mathematics, 2025, vol. 13, issue 13, 1-36

Abstract: Proton exchange membrane water electrolyzers (PEMWEs) are a promising technology for green hydrogen production. However, the adoption of PEMWE-based hydrogen production systems remains limited due to several challenges, including high material costs, limited performance and durability, and difficulties in scaling the technology. Computational modeling serves as a powerful tool to address these challenges by optimizing system design, improving material performance, and reducing overall costs, thereby accelerating the commercial rollout of PEMWE technology. Despite this, conventional models often oversimplify key components, such as porous transport and catalyst layers, by assuming constant porosity and neglecting the spatial heterogeneity found in real electrodes. This simplification can significantly impact the accuracy of performance predictions and the overall efficiency of electrolyzers. This study develops a mathematical framework for modeling variable porosity distributions—including constant, linearly graded, and stepwise profiles—and derives analytical expressions for permeability, effective diffusivity, and electrical conductivity. These functions are integrated into a three-dimensional multi-domain COMSOL simulation to assess their impact on electrochemical performance and transport behavior. The results reveal that although porosity variations have minimal effect on polarization at low voltages, they significantly influence internal pressure, species distribution, and gas evacuation at higher loads. A notable finding is that reversing stepwise porosity—placing high porosity near the membrane rather than the channel—can alleviate oxygen accumulation and improve current density. A multi-factor comparison highlights this reversed configuration as the most favorable among the tested strategies. The proposed modeling approach effectively connects porous media theory and system-level electrochemical analysis, offering a flexible platform for the future design of porous electrodes in PEMWE and other energy conversion systems.

Keywords: porosity modeling; spatial functions; analytical transport models; PEM water electrolyzer; multi-domain simulation; parametric sensitivity analysis (search for similar items in EconPapers)
JEL-codes: C (search for similar items in EconPapers)
Date: 2025
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