Investigation on Cycling and Calendar Aging Processes of 3.4 Ah Lithium-Sulfur Pouch Cells

Salimeh Gohari, Vaclav Knap and Mohammad Reza Yaftian
Additional contact information
Salimeh Gohari: Phase Equilibria Research Laboratory, Department of Chemistry, Faculty of Science, University of Zanjan, Zanjan 45371-38791, Iran
Vaclav Knap: Department of Energy Technology, Aalborg University, 9000 Aalborg, Denmark
Mohammad Reza Yaftian: Phase Equilibria Research Laboratory, Department of Chemistry, Faculty of Science, University of Zanjan, Zanjan 45371-38791, Iran

Sustainability, 2021, vol. 13, issue 16, 1-14

Abstract: Much attention has been paid to rechargeable lithium-sulfur batteries (Li–SBs) due to their high theoretical specific capacity, high theoretical energy density, and affordable cost. However, their rapid c fading capacity has been one of the key defects in their commercialization. It is believed that sulfuric cathode degradation is driven mainly by passivation of the cathode surface by Li 2 S at discharge, polysulfide shuttle (reducing the amount of active sulfur at the cathode, passivation of anode surface), and volume changes in the sulfuric cathode. These degradation mechanisms are significant during cycling, and the polysulfide shuttle is strongly present during storage at a high state-of-charge (SOC). Thus, storage at 50% SOC is used to evaluate the effect of the remaining degradation processes on the cell’s performance. In this work, unlike most of the other previous observations that were performed at small-scale cells (coin cells), 3.4 Ah pouch Li–SBs were tested using cycling and calendar aging protocols, and their performance indicators were analyzed. As expected, the fade capacity of the cycling aging cells was greater than that of the calendar aging cells. Additionally, the measurements for the calendar aging cells indicate that, contrary to the expectation of stopping the solubility of long-chain polysulfides and not attending the shuttle effect, these phenomena occur continuously under open-circuit conditions.

Keywords: lithium-sulfur batteries; calendar aging; cycling aging (search for similar items in EconPapers)
JEL-codes: O13 Q Q0 Q2 Q3 Q5 Q56 (search for similar items in EconPapers)
Date: 2021
References: View references in EconPapers View complete reference list from CitEc
Citations: View citations in EconPapers (2)

Downloads: (external link)
https://www.mdpi.com/2071-1050/13/16/9473/pdf (application/pdf)
https://www.mdpi.com/2071-1050/13/16/9473/ (text/html)

Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.

Export reference: BibTeX RIS (EndNote, ProCite, RefMan) HTML/Text

Persistent link: https://EconPapers.repec.org/RePEc:gam:jsusta:v:13:y:2021:i:16:p:9473-:d:620190

Access Statistics for this article

Sustainability is currently edited by Ms. Alexandra Wu

More articles in Sustainability from MDPI
Bibliographic data for series maintained by MDPI Indexing Manager ().