Preparation of Fe-Based MOFs Composite as an Adsorptive Photocatalyst with Enhanced Photo-Fenton Degradation under LED Light Irradiation

Patrick Armando, Valentino Bervia Lunardi, Felycia Edi Soetaredjo, Jindrayani Nyoo Putro, Shella Permatasari Santoso, Christian Julius Wijaya, Jenni Lie, Wenny Irawaty, Maria Yuliana, Hardy Shuwanto, Hairus Abdullah, I Gede Wenten and Suryadi Ismadji ()
Additional contact information
Patrick Armando: Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114, Indonesia
Valentino Bervia Lunardi: Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114, Indonesia
Felycia Edi Soetaredjo: Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114, Indonesia
Jindrayani Nyoo Putro: Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114, Indonesia
Shella Permatasari Santoso: Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114, Indonesia
Christian Julius Wijaya: Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114, Indonesia
Jenni Lie: Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114, Indonesia
Wenny Irawaty: Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114, Indonesia
Maria Yuliana: Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114, Indonesia
Hardy Shuwanto: Department of Industrial Engineering, Universitas Prima Indonesia, Medan 20117, Indonesia
Hairus Abdullah: Department of Industrial Engineering, Universitas Prima Indonesia, Medan 20117, Indonesia
I Gede Wenten: Department of Chemical Engineering, Institute of Technology Bandung (ITB), Jl. Ganesha 10, Bandung 40132, Indonesia
Suryadi Ismadji: Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Kalijudan 37, Surabaya 60114, Indonesia

Sustainability, 2022, vol. 14, issue 17, 1-24

Abstract: In this study, a novel MIL-100(Fe)@TiO 2 composite was synthesized and used as the adsorbent to remove Rhodamine B from synthetic wastewater through adsorption and photocatalytic degradation. The composite was synthesized successfully using solvothermal methods. MIL-100(Fe)@TiO 2 composite has excellent adsorption and photodegradation capability for Rhodamine B removal. The reusability of the materials was observed, with the conclusion that the material still had good adsorption and photocatalytic performance after five cycles of consecutive experiments. The adsorption isotherm, kinetic, and thermodynamic studies of the removal of Rhodamine B were also conducted. The Langmuir model represented the adsorption equilibrium data better than other models. The kinetics of adsorption of Rhodamine B was presented well by pseudo-first-order. The thermodynamic study verified that the physisorption mechanism was more dominant than chemisorption. The addition of Fenton was also proven to be successful in increasing the photocatalytic abilities of the synthesized materials.

Keywords: metal–organic framework; photocatalytic degradation; thermodynamic; composite (search for similar items in EconPapers)
JEL-codes: O13 Q Q0 Q2 Q3 Q5 Q56 (search for similar items in EconPapers)
Date: 2022
References: View complete reference list from CitEc
Citations:

Downloads: (external link)
https://www.mdpi.com/2071-1050/14/17/10685/pdf (application/pdf)
https://www.mdpi.com/2071-1050/14/17/10685/ (text/html)

Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.

Export reference: BibTeX RIS (EndNote, ProCite, RefMan) HTML/Text

Persistent link: https://EconPapers.repec.org/RePEc:gam:jsusta:v:14:y:2022:i:17:p:10685-:d:899355

Access Statistics for this article

Sustainability is currently edited by Ms. Alexandra Wu

More articles in Sustainability from MDPI
Bibliographic data for series maintained by MDPI Indexing Manager ().