Application of Magnesium Oxide for Metal Removal in Mine Water Treatment

Andrés Navarro () and María Izabel Martínez da Matta
Additional contact information
Andrés Navarro: Fluid Mechanics, Universitat Politècnica de Catalunya (UPC), Jordi Girona, 08034 Barcelona, Spain
María Izabel Martínez da Matta: Faculty of Biology, University of Barcelona, 08007 Barcelona, Spain

Sustainability, 2022, vol. 14, issue 23, 1-15

Abstract: In this study low-grade magnesium oxide (MgO) produced by calcinations of natural magnesite was used in mine water treatment using a laboratory-column device. The treatment of mine water from the abandoned Osor mine (NE Spain) with MgO showed the removal of metals from both mine water and tailing leachates. The PHREEQC numerical code and the Geochemist’s Workbench code (GWB) were used to evaluate the speciation of dissolved constituents and calculate the saturation state of the effluents. The analysis of the treated mine water showed the removal of As (from 1.59 to 0.31 μg/L), Cd (from 1.98 to <0.05 μg/L), Co (from 19.1 to <0.03 μg/L), F (from 2730 to 200 μg/L), Mn (from 841 to 0.6 μg/L), Ni (from 17.9 to <2 μg/L, U (from 9.16 to 0.08 μg/L), and Zn (from 2900 to 68.5 μg/L). Pb was also removed (from 98 to 35.2 μg/L) in the treatment of contaminated leachates from the mine waste. The mixing of MgO and water at room temperature may promote the formation of a stabilizing agent composed of hydroxides, carbonates, and magnesium-silicate-hydrates (MSH), which may remove Cd, Zn, and similar metals by sorption on MSH, substitution on the MSH lattice, and precipitation or co-precipitation with some of the hydrated phases.

Keywords: magnesium oxide; mine water treatment; circum-neutral mine water; geochemical modeling; metals; column test; leaching; PHREEQC (search for similar items in EconPapers)
JEL-codes: O13 Q Q0 Q2 Q3 Q5 Q56 (search for similar items in EconPapers)
Date: 2022
References: View references in EconPapers View complete reference list from CitEc
Citations:

Downloads: (external link)
https://www.mdpi.com/2071-1050/14/23/15857/pdf (application/pdf)
https://www.mdpi.com/2071-1050/14/23/15857/ (text/html)

Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.

Export reference: BibTeX RIS (EndNote, ProCite, RefMan) HTML/Text

Persistent link: https://EconPapers.repec.org/RePEc:gam:jsusta:v:14:y:2022:i:23:p:15857-:d:987029

Access Statistics for this article

Sustainability is currently edited by Ms. Alexandra Wu

More articles in Sustainability from MDPI
Bibliographic data for series maintained by MDPI Indexing Manager ().