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Effect of Temperature and Humidity on the Synthesis of Alkali-Activated Binders Based on Bottom Ash from Municipal Waste Incineration

Pietro C. D. Tortora, Alex Maldonado-Alameda, Jofre Mañosa, Alex C. Quintero-Payan, Cristina Leonelli, Isabella Lancellotti and Josep M. Chimenos
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Pietro C. D. Tortora: Department of Engineering “Enzo Ferrari”, University of Modena and Reggio Emilia, 41125 Modena, Italy
Alex Maldonado-Alameda: Departament de Ciència de Materials i Química Física, Universitat de Barcelona, 08028 Barcelona, Spain
Jofre Mañosa: Departament de Ciència de Materials i Química Física, Universitat de Barcelona, 08028 Barcelona, Spain
Alex C. Quintero-Payan: Departament de Ciència de Materials i Química Física, Universitat de Barcelona, 08028 Barcelona, Spain
Cristina Leonelli: Department of Engineering “Enzo Ferrari”, University of Modena and Reggio Emilia, 41125 Modena, Italy
Isabella Lancellotti: Department of Engineering “Enzo Ferrari”, University of Modena and Reggio Emilia, 41125 Modena, Italy
Josep M. Chimenos: Departament de Ciència de Materials i Química Física, Universitat de Barcelona, 08028 Barcelona, Spain

Sustainability, 2022, vol. 14, issue 3, 1-18

Abstract: Weathered bottom ash (WBA) from municipal solid waste incineration is a calcium aluminosilicate-rich material mainly used in construction and civil engineering as a secondary aggregate. However, its use is also being considered as a precursor in the manufacture of alkali-activated binders (AA-WBA). This preliminary research aimed to deepen understanding of the potential use of WBA (>8 mm fraction) as the sole precursor of alkali-activated binders. To gain better knowledge of this material, the physicochemical, mechanical, and environmental properties of AA-WBA binders were evaluated. In addition, the effect of curing temperature (25 °C, 45 °C, 65 °C, and 85 °C) and humidity conditions (oven and climate chamber) were assessed. The results of this study revealed that temperature and humidity conditions play a fundamental role during the early formation stages of AA-WBA binders. Maximum compactness and compressive strength (29.8 MPa) were obtained in the sample cured at 65 °C in the oven and room humidity. At higher temperatures (85 °C), a substantial decrease in mechanical strength (21.2 MPa) was observed due to a lower cohesion of the binder phases. Curing in the climate chamber led to an increase in humidity, and therefore a decrease in compressive strength. Finally, lower porosity and longer curing time substantially decreased the heavy metals and metalloid leaching concentration of AA-WBA binders.

Keywords: alkali-activated binders; incineration bottom ash; MSWI; weathered bottom ash; alternative cement; waste valorization (search for similar items in EconPapers)
JEL-codes: O13 Q Q0 Q2 Q3 Q5 Q56 (search for similar items in EconPapers)
Date: 2022
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