Hydrolysis Optimization of By-Products from the Potato Processing Industry and Biomethane Production from Starch Hydrolysates
Dimitra Theodosi Palimeri,
Konstantina Papadopoulou,
Apostolos G. Vlyssides and
Anestis A. Vlysidis ()
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Dimitra Theodosi Palimeri: School of Chemical Engineering, National Technical University of Athens, 15780 Athens, Greece
Konstantina Papadopoulou: School of Chemical Engineering, National Technical University of Athens, 15780 Athens, Greece
Apostolos G. Vlyssides: School of Chemical Engineering, National Technical University of Athens, 15780 Athens, Greece
Anestis A. Vlysidis: School of Chemical Engineering, National Technical University of Athens, 15780 Athens, Greece
Sustainability, 2023, vol. 15, issue 20, 1-20
Abstract:
This study aims to investigate the use of Fenton reagents for the efficient hydrolysis of starch, an industrial by-product obtained from the potato processing industry. A full factorial design experiment (FFD) was conducted and a statistical model was developed for simulating the hydrolysis process. The most important factors were the hydrolysis temperature and the amount of H 2 O 2 followed by the interaction of FeSO 4 ·7H 2 O and temperature. At maximum levels of FeSO 4 ·7H 2 O (1.00g/L), H 2 O 2 (0.51 g/L), and temperature (70.0 °C), a 99.5% hydrolysis yield was achieved, with a carbohydrate content of 28.65 g/L. Furthermore, analysis of hydrolysis kinetics demonstrated that an increased concentration of FeSO 4 ·7H 2 O results in a decelerated rate of starch hydrolysis. Moreover, biodegradability tests were carried out to estimate the methane production potential from the produced hydrolysates. The specific methanogenic activity (SMA) was reached at 0.669 ± 0.014 g CH 4 -COD g −1 VSS day −1 proving the effectiveness of the hydrolysis process and highlighting the potential of industrial starch for bioenergy production. A preliminary cost analysis showed that a small investment for utilizing the starch in an existing wastewater treatment facility of a potato processing company becomes profitable before the end of the 3rd year, obtaining a net present value (NPV) 37.5% higher than that of the current utilization scenario.
Keywords: starch hydrolysis; waste valorization; biomethane production; anaerobic digestion; potato processing industry; Fenton reagents (search for similar items in EconPapers)
JEL-codes: O13 Q Q0 Q2 Q3 Q5 Q56 (search for similar items in EconPapers)
Date: 2023
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Persistent link: https://EconPapers.repec.org/RePEc:gam:jsusta:v:15:y:2023:i:20:p:14860-:d:1259339
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