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Structural Characterization of Geopolymers with the Addition of Eggshell Ash

Marija Ivanović, Sanja Knežević (), Miljana M. Mirković, Ljiljana Kljajević, Dušan Bučevac, Vladimir B. Pavlović and Miloš Nenadović
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Marija Ivanović: Department of Materials, Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, University of Belgrade, Mike Petrović Alasa 12-14, Vinča, 11000 Belgrade, Serbia
Sanja Knežević: Department of Materials, Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, University of Belgrade, Mike Petrović Alasa 12-14, Vinča, 11000 Belgrade, Serbia
Miljana M. Mirković: Department of Materials, Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, University of Belgrade, Mike Petrović Alasa 12-14, Vinča, 11000 Belgrade, Serbia
Ljiljana Kljajević: Department of Materials, Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, University of Belgrade, Mike Petrović Alasa 12-14, Vinča, 11000 Belgrade, Serbia
Dušan Bučevac: Department of Materials, Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, University of Belgrade, Mike Petrović Alasa 12-14, Vinča, 11000 Belgrade, Serbia
Vladimir B. Pavlović: Institute of Technical Sciences of the Serbian Academy of Sciences and Arts, University of Belgrade, 11000 Belgrade, Serbia
Miloš Nenadović: Department of Atomics Physics, Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, Mike Petrović Alasa 12-14, Vinča, 11000 Belgrade, Serbia

Sustainability, 2023, vol. 15, issue 6, 1-13

Abstract: It is well known that geopolymers are a new group of binder materials of alumosilicate origin. Geopolymers are made by the reaction of precursor aluminosilicate materials with alkaline activator solutions. The current research relates to a low-cost and eco-friendly procedure, suitable of being implemented in two easy steps. The first step is the production of a solid phase based on fly ash (Obrenovac, Serbia) and eggshell ash as waste materials rich in calcium. The second step is alkali activating the solid phase using an alkaline activator (a mixture of NaOH and Na 2 SiO 3 ) and procedures in proper laboratory conditions. Four samples with different eggshell ash content were synthesized. The concentration of used NaOH was 12 mol dm −3 . The structural properties of all investigated samples were analyzed by XRD ( X-ray diffraction ), DRIFT ( diffuse reflectance infrared Fourier transform ), SEM ( scanning electron microscopy ) and UV/Vis spectroscopy analysis. XRD determined the amorphous halo with the presence of quartz as the crystal phase in all of the investigated samples. These results were confirmed by DRIFT analysis. The morphology of the samples was determined by SEM analysis. UV/Vis showed that the material could be a potential adsorbent.

Keywords: alkali-activated; geopolymer; fly ash; eggshell ash; DRIFT; XRD; SEM; UV/Vis (search for similar items in EconPapers)
JEL-codes: O13 Q Q0 Q2 Q3 Q5 Q56 (search for similar items in EconPapers)
Date: 2023
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