Effects of Pyrolysis and Activation Conditions on SO 2 and NO Adsorption by Biochar and Its Environmental Impact
Kyungil Cho,
Hyeonrok Choi and
Yongwoon Lee ()
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Kyungil Cho: Research Institute of Sustainable Development Technology, Korea Institute of Industrial Technology, Cheonan 31056, Republic of Korea
Hyeonrok Choi: Research Institute of Sustainable Development Technology, Korea Institute of Industrial Technology, Cheonan 31056, Republic of Korea
Yongwoon Lee: Research Institute of Sustainable Development Technology, Korea Institute of Industrial Technology, Cheonan 31056, Republic of Korea
Sustainability, 2025, vol. 17, issue 13, 1-18
Abstract:
This study investigates the adsorption performance of biochar synthesized under varying pyrolysis and CO 2 activation conditions for the simultaneous removal of nitrogen monoxide (NO) and sulfur dioxide (SO 2 ), with an additional focus on its environmental impacts via life cycle assessment (LCA). Biochar was produced from Hinoki cypress using a two-stage process comprising initial pyrolysis followed by CO 2 activation, and its physicochemical properties were evaluated through pore structure analysis. Adsorption experiments were conducted under both single- and combined-gas conditions to assess the synergistic or competitive behaviors of NO and SO 2 adsorption. The results indicated that activation conditions significantly influenced the surface area and pore volume of biochar, leading to enhanced gas adsorption capacities. A trade-off between biochar yield and pollutant removal efficiency was observed, suggesting an optimal activation temperature balancing these two factors. Furthermore, the LCA approach, employing IPCC 2021 GWP 100 metrics, quantified the environmental impacts of biochar production under different thermal conditions. The findings revealed that although higher activation temperatures improved adsorption efficiency, they also resulted in increased energy consumption and associated greenhouse gas emissions. These outcomes demonstrate the necessity of optimizing activation parameters not only for functional performance but also for environmental sustainability. This work provides insight into designing efficient biochar-based gas treatment systems and supports their potential application as eco-friendly alternatives in industrial emission control strategies.
Keywords: biochar; pyrolysis; activation; adsorption; air pollutants; life cycle assessment (search for similar items in EconPapers)
JEL-codes: O13 Q Q0 Q2 Q3 Q5 Q56 (search for similar items in EconPapers)
Date: 2025
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Persistent link: https://EconPapers.repec.org/RePEc:gam:jsusta:v:17:y:2025:i:13:p:6137-:d:1694599
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