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Liquid-Liquid Equilibrium of the Ternary System Water/Formic Acid/1-Pentanol at T= 308.2 K

Hossein Ghanadzadeh, Shahin Asan and Milad Sangashekan
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Hossein Ghanadzadeh: University of Guilan, Rasht, Iran
Shahin Asan: University of Urmia, Urmia, Iran
Milad Sangashekan: University of Guilan, Rasht, Iran

International Journal of Chemoinformatics and Chemical Engineering (IJCCE), 2013, vol. 3, issue 2, 85-93

Abstract: Liquid–liquid equilibrium data for the (water + Formic acid + 1-pentanol) ternary system were determined at T = (308.2) K in ambient pressure. This ternary system exhibits type-1 behavior of LLE. Distribution coefficients and separation factors were measured to evaluate the extracting capacity of the solvent. The consistency of the experimental tie-line data was determined through the Othmer–Tobias and Bachman equations. The raw experimental data were correlated using the NRTL and UNIQUAC models. The average root-mean-square deviation between the experimental and calculated mass fractions was 0.488% and 0.465%.

Date: 2013
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