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Solution-processed intermediate-band solar cells with lead sulfide quantum dots and lead halide perovskites

Hiroji Hosokawa (), Ryo Tamaki, Takuya Sawada, Akinori Okonogi, Haruyuki Sato, Yuhei Ogomi, Shuzi Hayase, Yoshitaka Okada and Toshihiro Yano
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Hiroji Hosokawa: Kao Corporation
Ryo Tamaki: The University of Tokyo
Takuya Sawada: Kao Corporation
Akinori Okonogi: Kao Corporation
Haruyuki Sato: Kao Corporation
Yuhei Ogomi: Kyushu Institute of Technology
Shuzi Hayase: Kyushu Institute of Technology
Yoshitaka Okada: The University of Tokyo
Toshihiro Yano: Kao Corporation

Nature Communications, 2019, vol. 10, issue 1, 1-8

Abstract: Abstract The intermediate-band solar cell (IBSC) with quantum dots and a bulk semiconductor matrix has potential for high power conversion efficiency, exceeding the Shockley-Queisser limit. However, the IBSCs reported to date have been fabricated only by dry process and their efficiencies are limited, because their photo-absorption layers have low particle density of quantum dots, defects due to lattice strain, and low bandgap energy of bulk semiconductors. Here we present solution-processed IBSCs containing photo-absorption layers where lead sulfide quantum dots are densely dispersed in methylammonium lead bromide perovskite matrices with a high bandgap energy of 2.3 eV under undistorted conditions. We confirm that the present IBSCs exhibit two-step photon absorption via intermediate-band at room temperature by inter-subband photocurrent spectroscopy.

Date: 2019
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DOI: 10.1038/s41467-018-07655-3

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