Enzymatic synthesis of lignin derivable pyridine based polyesters for the substitution of petroleum derived plastics

Alessandro Pellis (), James W. Comerford, Simone Weinberger, Georg M. Guebitz, James H. Clark and Thomas J. Farmer ()
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Alessandro Pellis: Green Chemistry Centre of Excellence
James W. Comerford: Green Chemistry Centre of Excellence
Simone Weinberger: Institute of Environmental Biotechnology
Georg M. Guebitz: Institute of Environmental Biotechnology
James H. Clark: Green Chemistry Centre of Excellence
Thomas J. Farmer: Green Chemistry Centre of Excellence

Nature Communications, 2019, vol. 10, issue 1, 1-9

Abstract: Abstract Following concerns over increasing global plastic pollution, interest in the production and characterization of bio-based and biodegradable alternatives is rising. In the present work, the synthesis of a series of fully bio-based alternatives based on 2,4-, 2,5-, and 2,6-pyridinedicarboxylic acid-derived polymers produced via enzymatic catalysis are reported. A similar series of aromatic-aliphatic polyesters based on diethyl-2,5-furandicarboxylate and of the petroleum-based diethyl terephthalate and diethyl isophthalate were also synthesized. Here we show that the enzymatic synthesis starting from 2,4-diethyl pyridinedicarboxylate leads to the best polymers in terms of molecular weights (Mn = 14.3 and Mw of 32.1 kDa when combined with 1,8-octanediol) when polymerized in diphenyl ether. Polymerization in solventless conditions were also successful leading to the synthesis of bio-based oligoesters that can be further functionalized. DSC analysis show a clear similarity in the thermal behavior between 2,4-diethyl pyridinedicarboxylate and diethyl isophthalate (amorphous polymers) and between 2,5-diethyl pyridinedicarboxylate and diethyl terephthalate (crystalline polymers).

Date: 2019
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DOI: 10.1038/s41467-019-09817-3

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