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Chemically modified graphene films with tunable negative Poisson’s ratios

Yeye Wen, Enlai Gao, Zhenxing Hu, Tingge Xu, Hongbing Lu, Zhiping Xu () and Chun Li ()
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Yeye Wen: Tsinghua University
Enlai Gao: Wuhan University
Zhenxing Hu: The University of Texas at Dallas
Tingge Xu: The University of Texas at Dallas
Hongbing Lu: The University of Texas at Dallas
Zhiping Xu: Tsinghua University
Chun Li: Tsinghua University

Nature Communications, 2019, vol. 10, issue 1, 1-8

Abstract: Abstract Graphene-derived macroscopic assemblies feature hierarchical nano- and microstructures that provide numerous routes for surface and interfacial functionalization achieving unconventional material properties. We report that the microstructural hierarchy of pristine chemically modified graphene films, featuring wrinkles, delamination of close-packed laminates, their ordered and disordered stacks, renders remarkable negative Poisson’s ratios ranging from −0.25 to −0.55. The mechanism proposed is validated by the experimental characterization and theoretical analysis. Based on the understanding of microstructural origins, pre-strech is applied to endow chemically modified graphene films with controlled negative Poisson’s ratios. Modulating the wavy textures of the inter-connected network of close-packed laminates in the chemically modified graphene films also yields finely-tuned negative Poisson’s ratios. These findings offer the key insights into rational design of films constructed from two-dimensional materials with negative Poisson’s ratios and mechanomutable performance.

Date: 2019
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DOI: 10.1038/s41467-019-10361-3

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