Solid solution for catalytic ammonia synthesis from nitrogen and hydrogen gases at 50 °C

Masashi Hattori, Shinya Iijima, Takuya Nakao, Hideo Hosono () and Michikazu Hara ()
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Masashi Hattori: Laboratory for Materials and Structures, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku
Shinya Iijima: Laboratory for Materials and Structures, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku
Takuya Nakao: Materials Research Center for Element Strategy, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku
Hideo Hosono: Materials Research Center for Element Strategy, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku
Michikazu Hara: Laboratory for Materials and Structures, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku

Nature Communications, 2020, vol. 11, issue 1, 1-8

Abstract: Abstract The lack of efficient catalysts for ammonia synthesis from N2 and H2 gases at the lower temperature of ca. 50 °C has been a problem not only for the Haber–Bosch process, but also for ammonia production toward zero CO2 emissions. Here, we report a new approach for low temperature ammonia synthesis that uses a stable electron-donating heterogeneous catalyst, cubic CaFH, a solid solution of CaF2 and CaH2 formed at low temperatures. The catalyst produced ammonia from N2 and H2 gases at 50 °C with an extremely small activation energy of 20 kJ mol−1, which is less than half that for conventional catalysts reported. The catalytic performance can be attributed to the weak ionic bonds between Ca2+ and H− ions in the solid solution and the facile release of hydrogen atoms from H− sites.

Date: 2020
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DOI: 10.1038/s41467-020-15868-8

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