Highly efficient phosphor-glass composites by pressureless sintering
Dao Zhang,
Wenge Xiao (),
Chang Liu,
Xiaofeng Liu,
Jinjun Ren,
Beibei Xu and
Jianrong Qiu ()
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Dao Zhang: Zhejiang University
Wenge Xiao: Zhejiang University
Chang Liu: Zhejiang University
Xiaofeng Liu: Zhejiang University
Jinjun Ren: Chinese Academy of Sciences
Beibei Xu: Zhejiang University
Jianrong Qiu: Zhejiang University
Nature Communications, 2020, vol. 11, issue 1, 1-8
Abstract:
Abstract The development of high-power white light-emitting diodes demands highly efficient and stable all-inorganic color converters. In this respect, phosphor-glass/ceramic composites show great promise as they could combine the merits of high quantum efficiency of phosphors and high chemical and thermal stabilities of glass/ceramic matrices. However, strong interfacial reaction between phosphors and matrices at high temperature results in quantum efficiency loss of the embedded phosphors, and traditional solutions rely on high-pressure consolidation techniques. Here we report the intrinsic inhibition of interfacial reaction by using silica glass rather than multicomponent glasses as the matrix. The embedment of phosphors is achieved via a pressureless sintering method, rendering these color-tunable phosphor-glass composites not only accessible to three-dimensional printing technique, but also highly efficient (internal quantum efficiency >90.0%), thermally stable at 1200 °C and hydrothermally stable at 200 °C. Our results provide a facile and general strategy for developing all-inorganic functional composites.
Date: 2020
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Persistent link: https://EconPapers.repec.org/RePEc:nat:natcom:v:11:y:2020:i:1:d:10.1038_s41467-020-16649-z
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DOI: 10.1038/s41467-020-16649-z
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