Spontaneous solar water splitting with decoupling of light absorption and electrocatalysis using silicon back-buried junction

Hui-Chun Fu, Purushothaman Varadhan, Chun-Ho Lin and Jr-Hau He ()
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Hui-Chun Fu: Computer, Electrical, and Mathematical Sciences and Engineering, King Abdullah University of Science and Technology, (KAUST)
Purushothaman Varadhan: Computer, Electrical, and Mathematical Sciences and Engineering, King Abdullah University of Science and Technology, (KAUST)
Chun-Ho Lin: Computer, Electrical, and Mathematical Sciences and Engineering, King Abdullah University of Science and Technology, (KAUST)
Jr-Hau He: Computer, Electrical, and Mathematical Sciences and Engineering, King Abdullah University of Science and Technology, (KAUST)

Nature Communications, 2020, vol. 11, issue 1, 1-9

Abstract: Abstract Converting sunlight into a storable form of energy by spontaneous water splitting is of great interest but the difficulty in simultaneous management of optical, electrical, and catalytic properties has limited the efficiency of photoelectrochemical (PEC) devices. Herein, we implemented a decoupling scheme of light harvesting and electrocatalysis by employing a back-buried junction (BBJ) PEC cell design, which enables >95% front side light-harvesting, whereas the electrochemical reaction in conjunction with carrier separation/transport/collection occurs on the back side of the PEC cell. The resultant silicon BBJ-PEC half-cell produces a current density of 40.51 mA cm−2 for hydrogen evolution by minimizing optical, electrical, and catalytic losses (as low as 6.11, 1.76, and 1.67 mA cm−2, respectively). Monolithic fabrication also enables three BBJ-PEC cells to be connected in series as a single module, enabling unassisted solar water-splitting with a solar-to-hydrogen conversion efficiency of 15.62% and a hydrogen generation rate of 240 μg cm−2 h−1.

Date: 2020
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DOI: 10.1038/s41467-020-17660-0

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