Chiroptical spectroscopy of a freely diffusing single nanoparticle

Johannes Sachs, Jan-Philipp Günther, Andrew G. Mark and Peer Fischer ()
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Johannes Sachs: Max Planck Institute for Intelligent Systems
Jan-Philipp Günther: Max Planck Institute for Intelligent Systems
Andrew G. Mark: Max Planck Institute for Intelligent Systems
Peer Fischer: Max Planck Institute for Intelligent Systems

Nature Communications, 2020, vol. 11, issue 1, 1-7

Abstract: Abstract Chiral plasmonic nanoparticles can exhibit strong chiroptical signals compared to the corresponding molecular response. Observations are, however, generally restricted to measurements on stationary single particles with a fixed orientation, which complicates the spectral analysis. Here, we report the spectroscopic observation of a freely diffusing single chiral nanoparticle in solution. By acquiring time-resolved circular differential scattering signals we show that the spectral interpretation is significantly simplified. We experimentally demonstrate the equivalence between time-averaged chiral spectra observed for an individual nanostructure and the corresponding ensemble spectra, and thereby demonstrate the ergodic principle for chiroptical spectroscopy. We also show how it is possible for an achiral particle to yield an instantaneous chiroptical response, whereas the time-averaged signals are an unequivocal measure of chirality. Time-resolved chiroptical spectroscopy on a freely moving chiral nanoparticle advances the field of single-particle spectroscopy, and is a means to obtain the true signature of the nanoparticle’s chirality.

Date: 2020
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DOI: 10.1038/s41467-020-18166-5

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