Insights on forming N,O-coordinated Cu single-atom catalysts for electrochemical reduction CO2 to methane

Yanming Cai, Jiaju Fu, Yang Zhou, Yu-Chung Chang, Qianhao Min (), Jun-Jie Zhu, Yuehe Lin () and Wenlei Zhu ()
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Yanming Cai: Nanjing University
Jiaju Fu: Nanjing University
Yang Zhou: School of Mechanical and Materials Engineering, Washington State University
Yu-Chung Chang: School of Mechanical and Materials Engineering, Washington State University
Qianhao Min: Nanjing University
Jun-Jie Zhu: Nanjing University
Yuehe Lin: School of Mechanical and Materials Engineering, Washington State University
Wenlei Zhu: School of Mechanical and Materials Engineering, Washington State University

Nature Communications, 2021, vol. 12, issue 1, 1-9

Abstract: Abstract Single-atom catalysts (SACs) are promising candidates to catalyze electrochemical CO2 reduction (ECR) due to maximized atomic utilization. However, products are usually limited to CO instead of hydrocarbons or oxygenates due to unfavorable high energy barrier for further electron transfer on synthesized single atom catalytic sites. Here we report a novel partial-carbonization strategy to modify the electronic structures of center atoms on SACs for lowering the overall endothermic energy of key intermediates. A carbon-dots-based SAC margined with unique CuN2O2 sites was synthesized for the first time. The introduction of oxygen ligands brings remarkably high Faradaic efficiency (78%) and selectivity (99% of ECR products) for electrochemical converting CO2 to CH4 with current density of 40 mA·cm-2 in aqueous electrolytes, surpassing most reported SACs which stop at two-electron reduction. Theoretical calculations further revealed that the high selectivity and activity on CuN2O2 active sites are due to the proper elevated CH4 and H2 energy barrier and fine-tuned electronic structure of Cu active sites.

Date: 2021
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DOI: 10.1038/s41467-020-20769-x

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