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Textured ferroelectric ceramics with high electromechanical coupling factors over a broad temperature range

Shuai Yang, Jinglei Li (), Yao Liu, Mingwen Wang, Liao Qiao, Xiangyu Gao, Yunfei Chang, Hongliang Du, Zhuo Xu, Shujun Zhang and Fei Li ()
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Shuai Yang: Xi’an Jiaotong University
Jinglei Li: Xi’an Jiaotong University
Yao Liu: Xi’an Jiaotong University
Mingwen Wang: Xi’an Jiaotong University
Liao Qiao: Xi’an Jiaotong University
Xiangyu Gao: Xi’an Jiaotong University
Yunfei Chang: Harbin Institute of Technology
Hongliang Du: Xi’an Jiaotong University
Zhuo Xu: Xi’an Jiaotong University
Shujun Zhang: AIIM, University of Wollongong
Fei Li: Xi’an Jiaotong University

Nature Communications, 2021, vol. 12, issue 1, 1-10

Abstract: Abstract The figure-of-merits of ferroelectrics for transducer applications are their electromechanical coupling factor and the operable temperature range. Relaxor-PbTiO3 ferroelectric crystals show a much improved electromechanical coupling factor k33 (88~93%) compared to their ceramic counterparts (65~78%) by taking advantage of the strong anisotropy of crystals. However, only a few relaxor-PbTiO3 systems, for example Pb(In1/2Nb1/2)O3-Pb(Mg1/3Nb2/3)O3-PbTiO3, can be grown into single crystals, whose operable temperature range is limited by their rhombohedral-tetragonal phase transition temperatures (Trt: 60~120 °C). Here, we develop a templated grain-growth approach to fabricate -textured Pb(In1/2Nb1/2)O3-Pb(Sc1/2Nb1/2)O3-PbTiO3 (PIN-PSN-PT) ceramics that contain a large amount of the refractory component Sc2O3, which has the ability to increase the Trt of the system. The high k33 of 85~89% and the greatly increased Trt of 160~200 °C are simultaneously achieved in the textured PIN-PSN-PT ceramics. The above merits will make textured PIN-PSN-PT ceramics an alternative to single crystals, benefiting the development of numerous advanced piezoelectric devices.

Date: 2021
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DOI: 10.1038/s41467-021-21673-8

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