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Half-Heusler-like compounds with wide continuous compositions and tunable p- to n-type semiconducting thermoelectrics

Zirui Dong, Jun Luo (), Chenyang Wang, Ying Jiang, Shihua Tan, Yubo Zhang, Yuri Grin, Zhiyang Yu, Kai Guo, Jiye Zhang and Wenqing Zhang ()
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Zirui Dong: Shanghai University
Jun Luo: Shanghai University
Chenyang Wang: Shanghai University
Ying Jiang: Materials Genome Institute, Shanghai University
Shihua Tan: Southern University of Science and Technology
Yubo Zhang: Southern University of Science and Technology
Yuri Grin: Max-Planck-Institut für Chemische Physik fester Stoffe
Zhiyang Yu: Fuzhou University
Kai Guo: Shanghai University
Jiye Zhang: Shanghai University
Wenqing Zhang: Southern University of Science and Technology

Nature Communications, 2022, vol. 13, issue 1, 1-9

Abstract: Abstract Half-Heusler and full-Heusler compounds were considered as independent phases with a natural composition gap. Here we report the discovery of TiRu1+xSb (x = 0.15 ~ 1.0) solid solution with wide homogeneity range and tunable p- to n-type semiconducting thermoelectrics, which bridges the composition gap between half- and full-Heusler phases. At the high-Ru end, strange glass-like thermal transport behavior with unusually low lattice thermal conductivity (~1.65 Wm−1K−1 at 340 K) is observed for TiRu1.8Sb, being the lowest among reported half-Heusler phases. In the composition range of 0.15

Date: 2022
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DOI: 10.1038/s41467-021-27795-3

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