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Ultralow-temperature-driven water-based sorption refrigeration enabled by low-cost zeolite-like porous aluminophosphate

Zhangli Liu, Jiaxing Xu, Min Xu (), Caifeng Huang, Ruzhu Wang, Tingxian Li () and Xiulan Huai ()
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Zhangli Liu: Chinese Academy of Sciences
Jiaxing Xu: Shanghai Jiao Tong University
Min Xu: Chinese Academy of Sciences
Caifeng Huang: Chinese Academy of Sciences
Ruzhu Wang: Shanghai Jiao Tong University
Tingxian Li: Shanghai Jiao Tong University
Xiulan Huai: Chinese Academy of Sciences

Nature Communications, 2022, vol. 13, issue 1, 1-10

Abstract: Abstract Thermally driven water-based sorption refrigeration is considered a promising strategy to realize near-zero-carbon cooling applications by addressing the urgent global climate challenge caused by conventional chlorofluorocarbon (CFC) refrigerants. However, developing cost-effective and high-performance water-sorption porous materials driven by low-temperature thermal energy is still a significant challenge. Here, we propose a zeolite-like aluminophosphate with SFO topology (EMM-8) for water-sorption-driven refrigeration. The EMM-8 is characterized by 12-membered ring channels with large accessible pore volume and exhibits high water uptake of 0.28 g·g−1 at P/P0 = 0.2, low-temperature regeneration of 65 °C, fast adsorption kinetics, remarkable hydrothermal stability, and scalable fabrication. Importantly, the water-sorption-based chiller with EMM-8 shows the potential of achieving a record coefficient of performance (COP) of 0.85 at an ultralow-driven temperature of 63 °C. The working performance makes EMM-8 a practical alternative to realize high-efficient ultra-low-temperature-driven refrigeration.

Date: 2022
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DOI: 10.1038/s41467-021-27883-4

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