Electrostatically cooperative host-in-host of metal cluster ⊂ ionic organic cages in nanopores for enhanced catalysis

Liangxiao Tan, Jun-Hao Zhou, Jian-Ke Sun () and Jiayin Yuan ()
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Liangxiao Tan: Beijing Institute of Technology
Jun-Hao Zhou: Beijing Institute of Technology
Jian-Ke Sun: Beijing Institute of Technology
Jiayin Yuan: Stockholm University

Nature Communications, 2022, vol. 13, issue 1, 1-8

Abstract: Abstract The construction of hierarchically nanoporous composite for high-performance catalytic application is still challenging. In this work, a series of host-in-host ionic porous materials are crafted by encapsulating ionic organic cages into a hyper-crosslinked, oppositely charged porous poly(ionic liquid) (PoPIL) through an ion pair-directed assembly strategy. Specifically, the cationic cage (C-Cage) as the inner host can spatially accommodate a functional Au cluster, forming a [Au⊂C-Cage+]⊂PoPIL− supramolecular composite. This dual-host molecular hierarchy enables a charge-selective substrate sorting effect to the Au clusters, which amplifies their catalytic activity by at least one order of magnitude as compared to Au confined only by C-Cage as the mono-host (Au⊂C-Cage+). Moreover, we demonstrate that such dual-host porous system can advantageously immobilize electrostatically repulsive Au⊂C-Cage+ and cationic ferrocene co-catalyst (Fer+) together into the same microcompartments, and synergistically speed up the enzyme-like tandem reactions by channelling the substrate to the catalytic centers via nanoconfinement.

Date: 2022
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DOI: 10.1038/s41467-022-29031-y

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