An intermetallic molecular nanomagnet with the lanthanide coordinated only by transition metals
Michał Magott,
Maria Brzozowska,
Stanisław Baran,
Veacheslav Vieru and
Dawid Pinkowicz ()
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Michał Magott: Jagiellonian University
Maria Brzozowska: Jagiellonian University
Stanisław Baran: Jagiellonian University
Veacheslav Vieru: Maastricht University
Dawid Pinkowicz: Jagiellonian University
Nature Communications, 2022, vol. 13, issue 1, 1-7
Abstract:
Abstract Magnetic molecules known as molecular nanomagnets (MNMs) may be the key to ultra-high density data storage. Thus, novel strategies on how to design MNMs are desirable. Here, inspired by the hexagonal structure of the hardest intermetallic magnet SmCo5, we have synthesized a nanomagnetic molecule where the central lanthanide (Ln) ErIII is coordinated solely by three transition metal ions (TM) in a perfectly trigonal planar fashion. This intermetallic molecule [ErIII(ReICp2)3] (ErRe3) starts a family of molecular nanomagnets (MNM) with unsupported Ln-TM bonds and paves the way towards molecular intermetallics with strong direct magnetic exchange interactions—a promising route towards high-performance single-molecule magnets.
Date: 2022
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Persistent link: https://EconPapers.repec.org/RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29624-7
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DOI: 10.1038/s41467-022-29624-7
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