Unlocking bimetallic active sites via a desalination strategy for photocatalytic reduction of atmospheric carbon dioxide

Xuezhen Feng, Renji Zheng, Caiyan Gao, Wenfei Wei, Jiangguli Peng, Ranhao Wang, Songhe Yang, Wensong Zou, Xiaoyong Wu (), Yongfei Ji and Hong Chen ()
Additional contact information
Xuezhen Feng: State Environmental Protection Key Laboratory of Integrated Surface Water Groundwater Pollution Control, Guangdong Provincial Key Laboratory of Soil and Groundwater Pollution Control, Key Laboratory of Municipal Solid Waste Recycling Technology and Management of Shenzhen City, Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials (SKLISEM), School of Environmental Science and Engineering, Southern University of Science and Technology
Renji Zheng: State Environmental Protection Key Laboratory of Integrated Surface Water Groundwater Pollution Control, Guangdong Provincial Key Laboratory of Soil and Groundwater Pollution Control, Key Laboratory of Municipal Solid Waste Recycling Technology and Management of Shenzhen City, Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials (SKLISEM), School of Environmental Science and Engineering, Southern University of Science and Technology
Caiyan Gao: Hubei Key Laboratory of Mineral Resources Processing and Environment, School of Resources and Environmental Engineering, Wuhan University of Technology
Wenfei Wei: State Environmental Protection Key Laboratory of Integrated Surface Water Groundwater Pollution Control, Guangdong Provincial Key Laboratory of Soil and Groundwater Pollution Control, Key Laboratory of Municipal Solid Waste Recycling Technology and Management of Shenzhen City, Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials (SKLISEM), School of Environmental Science and Engineering, Southern University of Science and Technology
Jiangguli Peng: State Environmental Protection Key Laboratory of Integrated Surface Water Groundwater Pollution Control, Guangdong Provincial Key Laboratory of Soil and Groundwater Pollution Control, Key Laboratory of Municipal Solid Waste Recycling Technology and Management of Shenzhen City, Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials (SKLISEM), School of Environmental Science and Engineering, Southern University of Science and Technology
Ranhao Wang: State Environmental Protection Key Laboratory of Integrated Surface Water Groundwater Pollution Control, Guangdong Provincial Key Laboratory of Soil and Groundwater Pollution Control, Key Laboratory of Municipal Solid Waste Recycling Technology and Management of Shenzhen City, Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials (SKLISEM), School of Environmental Science and Engineering, Southern University of Science and Technology
Songhe Yang: State Environmental Protection Key Laboratory of Integrated Surface Water Groundwater Pollution Control, Guangdong Provincial Key Laboratory of Soil and Groundwater Pollution Control, Key Laboratory of Municipal Solid Waste Recycling Technology and Management of Shenzhen City, Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials (SKLISEM), School of Environmental Science and Engineering, Southern University of Science and Technology
Wensong Zou: State Environmental Protection Key Laboratory of Integrated Surface Water Groundwater Pollution Control, Guangdong Provincial Key Laboratory of Soil and Groundwater Pollution Control, Key Laboratory of Municipal Solid Waste Recycling Technology and Management of Shenzhen City, Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials (SKLISEM), School of Environmental Science and Engineering, Southern University of Science and Technology
Xiaoyong Wu: Hubei Key Laboratory of Mineral Resources Processing and Environment, School of Resources and Environmental Engineering, Wuhan University of Technology
Yongfei Ji: School of Chemistry and Chemical Engineering, Guangzhou University
Hong Chen: State Environmental Protection Key Laboratory of Integrated Surface Water Groundwater Pollution Control, Guangdong Provincial Key Laboratory of Soil and Groundwater Pollution Control, Key Laboratory of Municipal Solid Waste Recycling Technology and Management of Shenzhen City, Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials (SKLISEM), School of Environmental Science and Engineering, Southern University of Science and Technology

Nature Communications, 2022, vol. 13, issue 1, 1-9

Abstract: Abstract Ultrathin two-dimensional (2D) metal oxyhalides exhibit outstanding photocatalytic properties with unique electronic and interfacial structures. Compared with monometallic oxyhalides, bimetallic oxyhalides are less explored. In this work, we have developed a novel top-down wet-chemistry desalination approach to remove the alkali-halide salt layer within the complicated precursor bulk structural matrix Pb0.6Bi1.4Cs0.6O2Cl2, and successfully fabricate a new 2D ultrathin bimetallic oxyhalide Pb0.6Bi1.4O2Cl1.4. The unlocked larger surface area, rich bimetallic active sites, and faster carrier dynamics within Pb0.6Bi1.4O2Cl1.4 layers significantly enhance the photocatalytic efficiency for atmospheric CO2 reduction. It outperforms the corresponding parental matrix phase and other state-of-the-art bismuth-based monometallic oxyhalides photocatalysts. This work reports a top-down desalination strategy to engineering ultrathin bimetallic 2D material for photocatalytic atmospheric CO2 reduction, which sheds light on further constructing other ultrathin 2D catalysts for environmental and energy applications from similar complicate structure matrixes.

Date: 2022
References: View references in EconPapers View complete reference list from CitEc
Citations:

Downloads: (external link)
https://www.nature.com/articles/s41467-022-29671-0 Abstract (text/html)

Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.

Export reference: BibTeX RIS (EndNote, ProCite, RefMan) HTML/Text

Persistent link: https://EconPapers.repec.org/RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29671-0

Ordering information: This journal article can be ordered from
https://www.nature.com/ncomms/

DOI: 10.1038/s41467-022-29671-0

Access Statistics for this article

Nature Communications is currently edited by Nathalie Le Bot, Enda Bergin and Fiona Gillespie

More articles in Nature Communications from Nature
Bibliographic data for series maintained by Sonal Shukla () and Springer Nature Abstracting and Indexing ().