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Scalable production of ultrafine polyaniline fibres for tactile organic electrochemical transistors

Bo Fang (), Jianmin Yan, Dan Chang, Jinli Piao, Kit Ming Ma, Qiao Gu, Ping Gao, Yang Chai () and Xiaoming Tao ()
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Bo Fang: The Hong Kong Polytechnic University
Jianmin Yan: The Hong Kong Polytechnic University
Dan Chang: Zhejiang University
Jinli Piao: The Hong Kong Polytechnic University
Kit Ming Ma: The Hong Kong Polytechnic University
Qiao Gu: The Hong Kong University of Science and Technology
Ping Gao: The Hong Kong University of Science and Technology
Yang Chai: The Hong Kong Polytechnic University
Xiaoming Tao: The Hong Kong Polytechnic University

Nature Communications, 2022, vol. 13, issue 1, 1-9

Abstract: Abstract The development of continuous conducting polymer fibres is essential for applications ranging from advanced fibrous devices to frontier fabric electronics. The use of continuous conducting polymer fibres requires a small diameter to maximize their electroactive surface, microstructural orientation, and mechanical strength. However, regularly used wet spinning techniques have rarely achieved this goal due primarily to the insufficient slenderization of rapidly solidified conducting polymer molecules in poor solvents. Here we report a good solvent exchange strategy to wet spin the ultrafine polyaniline fibres. The slow diffusion between good solvents distinctly decreases the viscosity of protofibers, which undergo an impressive drawing ratio. The continuously collected polyaniline fibres have a previously unattained diameter below 5 µm, high energy and charge storage capacities, and favorable mechanical performance. We demonstrated an ultrathin all-solid organic electrochemical transistor based on ultrafine polyaniline fibres, which operated as a tactile sensor detecting pressure and friction forces at different levels.

Date: 2022
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DOI: 10.1038/s41467-022-29773-9

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