Boosting electrocatalytic CO2–to–ethanol production via asymmetric C–C coupling

Pengtang Wang, Hao Yang, Cheng Tang, Yu Wu, Yao Zheng, Tao Cheng, Kenneth Davey, Xiaoqing Huang () and Shi-Zhang Qiao ()
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Pengtang Wang: The University of Adelaide
Hao Yang: Soochow University
Cheng Tang: The University of Adelaide
Yu Wu: Soochow University
Yao Zheng: The University of Adelaide
Tao Cheng: Soochow University
Kenneth Davey: The University of Adelaide
Xiaoqing Huang: Xiamen University
Shi-Zhang Qiao: The University of Adelaide

Nature Communications, 2022, vol. 13, issue 1, 1-11

Abstract: Abstract Electroreduction of carbon dioxide (CO2) into multicarbon products provides possibility of large-scale chemicals production and is therefore of significant research and commercial interest. However, the production efficiency for ethanol (EtOH), a significant chemical feedstock, is impractically low because of limited selectivity, especially under high current operation. Here we report a new silver–modified copper–oxide catalyst (dCu2O/Ag2.3%) that exhibits a significant Faradaic efficiency of 40.8% and energy efficiency of 22.3% for boosted EtOH production. Importantly, it achieves CO2–to–ethanol conversion under high current operation with partial current density of 326.4 mA cm−2 at −0.87 V vs reversible hydrogen electrode to rank highly significantly amongst reported Cu–based catalysts. Based on in situ spectra studies we show that significantly boosted production results from tailored introduction of Ag to optimize the coordinated number and oxide state of surface Cu sites, in which the *CO adsorption is steered as both atop and bridge configuration to trigger asymmetric C–C coupling for stablization of EtOH intermediates.

Date: 2022
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DOI: 10.1038/s41467-022-31427-9

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