Large area polymer semiconductor sub-microwire arrays by coaxial focused electrohydrodynamic jet printing for high-performance OFETs
Dazhi Wang (),
Liangkun Lu,
Zhiyuan Zhao,
Kuipeng Zhao,
Xiangyu Zhao,
Changchang Pu,
Yikang Li,
Pengfei Xu,
Xiangji Chen,
Yunlong Guo,
Liujia Suo,
Junsheng Liang,
Yan Cui and
Yunqi Liu
Additional contact information
Dazhi Wang: Dalian University of Technology
Liangkun Lu: Dalian University of Technology
Zhiyuan Zhao: Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences
Kuipeng Zhao: Dalian University of Technology
Xiangyu Zhao: Dalian University of Technology
Changchang Pu: Dalian University of Technology
Yikang Li: Dalian University of Technology
Pengfei Xu: Dalian University of Technology
Xiangji Chen: Dalian University of Technology
Yunlong Guo: Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences
Liujia Suo: Dalian University of Technology
Junsheng Liang: Dalian University of Technology
Yan Cui: Dalian University of Technology
Yunqi Liu: Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences
Nature Communications, 2022, vol. 13, issue 1, 1-9
Abstract:
Abstract Large area and highly aligned polymer semiconductor sub-microwires were fabricated using the coaxial focused electrohydrodynamic jet printing technology. As indicated by the results, the sub-microwire arrays have smooth morphology, well reproducibility and controllable with a width of ~110 nm. Analysis shows that the molecular chains inside the sub-microwires mainly exhibited edge-on arrangement and the π-stacking direction (010) of the majority of crystals is parallel to the long axis of the sub-microwires. Sub-microwires based organic field effect transistors showed high mobility with an average of 1.9 cm2 V−1 s−1, approximately 5 times higher than that of thin film based organic field effect transistors. In addition, the number of sub-microwires can be conveniently controlled by the printing technique, which can subsequently concisely control the performance of organic field effect transistors. This work demonstrates that sub-microwires fabricated by the coaxial focused electrohydrodynamic jet printing technology create an alternative path for the applications of high-performance organic flexible device.
Date: 2022
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DOI: 10.1038/s41467-022-34015-z
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