Circular polarized light-dependent anomalous photovoltaic effect from achiral hybrid perovskites

Tingting Zhu, Jie Bie, Chengmin Ji (), Xinyuan Zhang, Lina Li, Xitao Liu, Xiao-Ying Huang, Wei Fa, Shuang Chen and Junhua Luo ()
Additional contact information
Tingting Zhu: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Fuzhou
Jie Bie: Nanjing University
Chengmin Ji: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Fuzhou
Xinyuan Zhang: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Fuzhou
Lina Li: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Fuzhou
Xitao Liu: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Fuzhou
Xiao-Ying Huang: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Fuzhou
Wei Fa: Nanjing University
Shuang Chen: Nanjing University
Junhua Luo: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences Fuzhou

Nature Communications, 2022, vol. 13, issue 1, 1-8

Abstract: Abstract Circular polarized light-dependent anomalous bulk photovoltaic effect - a steady anomalous photovoltaic current can be manipulated by changing the light helicity, is an increasingly interesting topic in contexts ranging from physics to chemistry. Herein, circular polarized light-dependent anomalous bulk photovoltaic effect is presented in achiral hybrid perovskites, (4-AMP)BiI5 (ABI, 4-AMP is 4-(aminomethyl)piperidinium), breaking conventional realization that it can only happen in chiral species. Achiral hybrid perovskite ABI crystallizes in chiroptical-active asymmetric point group m (Cs), showing an anomalous bulk photovoltaic effect with giant photovoltage of 25 V, as well as strong circular polarized light - sensitive properties. Significantly, conspicuous circular polarized light-dependent anomalous bulk photovoltaic effect is reflected in the large degree of dependence of anomalous bulk photovoltaic effect on left-and right-CPL helicity, which is associated with left and right-handed screw optical axes of ABI. Such degree of dependence is demonstrated by a large asymmetry factor of 0.24, which almost falls around the highest value of hybrid perovskites. These unprecedented results may provide a perspective to develop opto-spintronic functionalities in hybrid perovskites.

Date: 2022
References: View references in EconPapers View complete reference list from CitEc
Citations:

Downloads: (external link)
https://www.nature.com/articles/s41467-022-35441-9 Abstract (text/html)

Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.

Export reference: BibTeX RIS (EndNote, ProCite, RefMan) HTML/Text

Persistent link: https://EconPapers.repec.org/RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-35441-9

Ordering information: This journal article can be ordered from
https://www.nature.com/ncomms/

DOI: 10.1038/s41467-022-35441-9

Access Statistics for this article

Nature Communications is currently edited by Nathalie Le Bot, Enda Bergin and Fiona Gillespie

More articles in Nature Communications from Nature
Bibliographic data for series maintained by Sonal Shukla () and Springer Nature Abstracting and Indexing ().