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Solution-grown BiI/BiI3 van der Waals heterostructures for sensitive X-ray detection

Renzhong Zhuang, Songhua Cai, Zengxia Mei, Huili Liang, Ningjiu Zhao, Haoran Mu, Wenzhi Yu, Yan Jiang, Jian Yuan, Shuping Lau, Shiming Deng, Mingyue Han, Peng Jin, Cailin Wang, Guangyu Zhang () and Shenghuang Lin ()
Additional contact information
Renzhong Zhuang: Songshan Lake Materials Laboratory
Songhua Cai: The Hong Kong Polytechnic University, Hunghom
Zengxia Mei: Songshan Lake Materials Laboratory
Huili Liang: Songshan Lake Materials Laboratory
Ningjiu Zhao: Songshan Lake Materials Laboratory
Haoran Mu: Songshan Lake Materials Laboratory
Wenzhi Yu: Songshan Lake Materials Laboratory
Yan Jiang: Songshan Lake Materials Laboratory
Jian Yuan: Songshan Lake Materials Laboratory
Shuping Lau: The Hong Kong Polytechnic University, Hunghom
Shiming Deng: HAMAMATSU Photonics (China) Co., LTD.
Mingyue Han: Songshan Lake Materials Laboratory
Peng Jin: Zhejiang University
Cailin Wang: Songshan Lake Materials Laboratory
Guangyu Zhang: Songshan Lake Materials Laboratory
Shenghuang Lin: Songshan Lake Materials Laboratory

Nature Communications, 2023, vol. 14, issue 1, 1-10

Abstract: Abstract X-ray detectors must be operated at minimal doses to reduce radiation health risks during X-ray security examination or medical inspection, therefore requiring high sensitivity and low detection limits. Although organolead trihalide perovskites have rapidly emerged as promising candidates for X-ray detection due to their low cost and remarkable performance, these materials threaten the safety of the human body and environment due to the presence of lead. Here we present the realization of highly sensitive X-ray detectors based on an environmentally friendly solution-grown thick BiI/BiI3/BiI (BixIy) van der Waals heterostructure. The devices exhibit anisotropic X-ray detection response with a sensitivity up to 4.3 × 104 μC Gy−1 cm−2 and a detection limit as low as 34 nGy s−1. At the same time, our BixIy detectors demonstrate high environmental and hard radiation stabilities. Our work motivates the search for new van der Waals heterostructure classes to realize high-performance X-ray detectors and other optoelectronic devices without employing toxic elements.

Date: 2023
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DOI: 10.1038/s41467-023-37297-z

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